引用本文:
高山, 刘世雄. 双核钒酰腙配合物[VO(C14H10N2O2]2(μ-O)的合成与表征[J]. 应用化学,
2001, 18(2): 161-162.
Citation: GAO Shan, LIU Shi-Xiong. Synthesis and Characterization of Dinuclear Vanadyl Hydrazone Complex[VO(C14H10N2O2)]2(μ-O)[J]. Chinese Journal of Applied Chemistry, 2001, 18(2): 161-162.
Citation: GAO Shan, LIU Shi-Xiong. Synthesis and Characterization of Dinuclear Vanadyl Hydrazone Complex[VO(C14H10N2O2)]2(μ-O)[J]. Chinese Journal of Applied Chemistry, 2001, 18(2): 161-162.
双核钒酰腙配合物[VO(C14H10N2O2]2(μ-O)的合成与表征
English
Synthesis and Characterization of Dinuclear Vanadyl Hydrazone Complex[VO(C14H10N2O2)]2(μ-O)
Abstract:
The dinuclear complex[VO(L)]2(_-O)(H2 L=salicylaldehyde benzoylhydrazone) was synthesized and characterized by elemental analysis, IR, UV, cyclic voltammetry. The results showed that two oxygen atoms and one nitrogen atom of the tridentate hydrazone ligand are coordinated to vanadium(V) atom. The vanadium atom approximates to a distorted square pyramidal coordination sphere. The redox potentials of the title complex in different solvents follow the order:CH2Cl2< CH3CN< DMF.
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Key words:
- oxovanadium(V) complex
- / hydrazone
- / synthesis
- / redox property
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