引用本文:
刘永红, 刘晓岚, 雷新有, 刘流, 王云普. 三苯膦(胂、䏲、䏟)配位次苄基九羰基三钴的合成及其催化活性[J]. 应用化学,
2001, 18(2): 146-148.
Citation: LIU Yong-Hong, LIU Xiao-Lan, LEI Xin-You, LIU Liu, WANG Yun-Pu. Synthesis and Hydroformylation Activity of Benzylidyne Noncarbonyl-tricobalt Complexes with Triphenylphosphine(Arsine,Stibine,Bismuthine)[J]. Chinese Journal of Applied Chemistry, 2001, 18(2): 146-148.
Citation: LIU Yong-Hong, LIU Xiao-Lan, LEI Xin-You, LIU Liu, WANG Yun-Pu. Synthesis and Hydroformylation Activity of Benzylidyne Noncarbonyl-tricobalt Complexes with Triphenylphosphine(Arsine,Stibine,Bismuthine)[J]. Chinese Journal of Applied Chemistry, 2001, 18(2): 146-148.
三苯膦(胂、䏲、䏟)配位次苄基九羰基三钴的合成及其催化活性
English
Synthesis and Hydroformylation Activity of Benzylidyne Noncarbonyl-tricobalt Complexes with Triphenylphosphine(Arsine,Stibine,Bismuthine)
Abstract:
Eight metal cluster compounds have been synthesized from parent compound (_3-CPh)Co3-(CO)9 and triphenylphosphine(arsine,stibine,bismuthine). All the compounds were characterized by elemental analysis and IR spectrometry. They results showed that their catalytic activities for 1-butene hydroformylation and the yields of product both were higher than that of the parent compound in 97% and 20% more, respectively, at reaction conditions of 303.5 K, 0.392 MPa, and for 48 hours. The catalytic activities and the ratio of nor to iso by using PhCCo3(CO)7(APh3)m were increased with increase in the atomic numbers of element A(A=P,As,Sb,Bi).
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Key words:
- benzylidyne noncarbon-tricobalt
- / triphenyl phosphine
- / hydroformylation
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