引用本文:
周光远, 程大军, 金国新. 取代茚基的茂金属Ti、Zr化合物的合成及其催化乙烯聚合活性[J]. 应用化学,
2001, 18(2): 128-130.
Citation: ZHOU Guang-Yuan, CHENG Da-Jun, JIN Guo-Xin. Synthesis of Metallocenes Containing Substituted Indenyl Ligand and Their Activity in Ethylene Polymerization[J]. Chinese Journal of Applied Chemistry, 2001, 18(2): 128-130.
Citation: ZHOU Guang-Yuan, CHENG Da-Jun, JIN Guo-Xin. Synthesis of Metallocenes Containing Substituted Indenyl Ligand and Their Activity in Ethylene Polymerization[J]. Chinese Journal of Applied Chemistry, 2001, 18(2): 128-130.
取代茚基的茂金属Ti、Zr化合物的合成及其催化乙烯聚合活性
English
Synthesis of Metallocenes Containing Substituted Indenyl Ligand and Their Activity in Ethylene Polymerization
Abstract:
The substituted indenyl metallocene complexes (1-C6H5CH2 Ind)2 MCl2(M=Ti(1),Zr(2)) and (1-C6H5CH2 Ind)CpMCl2(M=Ti(3),Zr(4)) were synthesized and characterizd by IR、1H NMR, EI-MS and elemental analysis. It is found that the compounds(2) and (4) could be used for catalytic polymerization of ethylene in the presence of MAO with products of [M]Z=(31.4~39.5)×104.
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Key words:
- metallocene
- / synthesis
- / olefin polymerization
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