引用本文:
李焰, 黄锦霞, 陈祖兴, 方国苏. 莰烷磺内酰胺法合成(R)和(S)黄粉虫性引诱信息素[J]. 应用化学,
2001, 18(10): 828-830.
Citation: LI Yan, HUANG Jin-Xia, CHEN Zu-Xing, FANG Guo-Su. Synthesis of the (R) and (S) Sex-Attractant of the Yellow Mealworn from Bornanesultam[J]. Chinese Journal of Applied Chemistry, 2001, 18(10): 828-830.
Citation: LI Yan, HUANG Jin-Xia, CHEN Zu-Xing, FANG Guo-Su. Synthesis of the (R) and (S) Sex-Attractant of the Yellow Mealworn from Bornanesultam[J]. Chinese Journal of Applied Chemistry, 2001, 18(10): 828-830.
莰烷磺内酰胺法合成(R)和(S)黄粉虫性引诱信息素
摘要:
黄粉虫(Tenebrio molitor L.)是一种危害粮食贮存的害虫.
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关键词:
- (R)和(S)-甲基-壬醇
- / 性引诱信息素
- / 莰烷磺内酰胺
- / 不对称烷基化反应
English
Synthesis of the (R) and (S) Sex-Attractant of the Yellow Mealworn from Bornanesultam
Abstract:
(R) and (S) 4-Methyl-1-nonanol, the sex attractant of the yellow mealworn(Tenebrio molitor L.), were synthesized from bornane-10,2-sultam via asymmetric alkylation of N-acylbornane-10,2-sultam with alkyl iodide, reductive cleavage with LiAlH4, bromination with HBr and reaction of organocuprate reagent with ethylene oxide in the presence of BF3·Et2O. The enantiomeric excess of the total syntheses was over 97%e.e..
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Key words:
- (R)and(S) methyl nonanol
- / sex attractant
- / N-acylbornane-sultam
- / asymmetric alkylation
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