引用本文:
许翩翩, 张藩贤, 王文峰, 彭亦如. Pd/C催化剂用于苯胺氧化羰基化[J]. 应用化学,
1997, 14(4): 41-45.
Citation: Xu Pianpian, Zhang Fanxian, Wang Wenfeng, Pen Yiru. Oxidative Carbonylation of Aniline by Pd/C Catalyst[J]. Chinese Journal of Applied Chemistry, 1997, 14(4): 41-45.
Citation: Xu Pianpian, Zhang Fanxian, Wang Wenfeng, Pen Yiru. Oxidative Carbonylation of Aniline by Pd/C Catalyst[J]. Chinese Journal of Applied Chemistry, 1997, 14(4): 41-45.
Pd/C催化剂用于苯胺氧化羰基化
English
Oxidative Carbonylation of Aniline by Pd/C Catalyst
Abstract:
The effects of the preparation conditions of Pd/C catalyst and the promoters on the catalytic property have been investigated. The influences of partial oxygen pressure and addition of nitrobenzene on the oxidative carbonylation of aniline to ethyl N-phenyl carbamate also have been tested. The Pd/C catalyst was characterized by XPS, TPR and in-situ IR techniques. A possible mechanism of the oxidative carbonylation of aniline catalyzed by Pd/C-NaI system in alcohol medium has been proposed.
-
Key words:
- aniline
- / oxidative carbonylation
- / ethyl N-phenyl carbamate
- / palladium
-
-
扫一扫看文章
计量
- PDF下载量: 0
- 文章访问数: 0
- HTML全文浏览量: 0

下载: