引用本文:
王曼芳, 步修仁, 孟庆金, 游效曾. 对-乙酰苯基二茂铁的晶体结构[J]. 应用化学,
1990, 7(4): 82-85.
Citation: Wang Manfang, Bu Xiuren, Meng Qingjin, You Xiaozeng. THE CRYSTAL STRUCTURE OF p-FERROCENYLACTEOPHENONE[J]. Chinese Journal of Applied Chemistry, 1990, 7(4): 82-85.
Citation: Wang Manfang, Bu Xiuren, Meng Qingjin, You Xiaozeng. THE CRYSTAL STRUCTURE OF p-FERROCENYLACTEOPHENONE[J]. Chinese Journal of Applied Chemistry, 1990, 7(4): 82-85.
对-乙酰苯基二茂铁的晶体结构
English
THE CRYSTAL STRUCTURE OF p-FERROCENYLACTEOPHENONE
Abstract:
The crystal and melecular structure of p-ferrocenylacetophenone has been determined by the single crystal X-ray diffractometry. The crystal is orthorhombic and space group Pbca with the cell constants a=7.7342, b=10.5485, c=34.0332Å and Z=8. The analytic results show that both the CP rings are almost parallel. The plane of each ring is tilt 18 from that of Phenyl ring.The carbon atom of the acetyl group is normal sp2 hybridization, the angles around this carbon is close to 120. One significant result obtained in this structure is that the carbon to carbon bond length in the CP ring linkedto the phenyl group is longer than C-C length in the other CP ring.
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Key words:
- p-ferrocenylacetophenone
- / crystal structure
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