引用本文:
于旻, 张淑清, 胡宝元, 金恕. 乙丙共物聚的结晶速率与序列结构[J]. 应用化学,
1989, 6(1): 22-25.
Citation: Yu Min, Zhang Shuqing, Hu Baoyuan, Jin Shu. CRYSTALLIZATION RATE AND SEQUENCE STRUCTURE OF ETHYLENE-PROPYLENE COPOLYMERS[J]. Chinese Journal of Applied Chemistry, 1989, 6(1): 22-25.
Citation: Yu Min, Zhang Shuqing, Hu Baoyuan, Jin Shu. CRYSTALLIZATION RATE AND SEQUENCE STRUCTURE OF ETHYLENE-PROPYLENE COPOLYMERS[J]. Chinese Journal of Applied Chemistry, 1989, 6(1): 22-25.
乙丙共物聚的结晶速率与序列结构
摘要:
本文用(体)热膨胀计法研究了共聚物组成、催化体系对乙丙共聚物结晶速率的影响。结果表明,同一催化体系乙丙共聚物的最大结晶速率(1/t1/2(max))随共聚物中乙烯含量的增加而增大。不同催化体系对二元乙丙共聚物的1/t(1/2)(max)次序为:VOCl3->V5-9->V(acac)3-。加入活化剂ETCA的各催化体系的二元乙丙共聚物的1/t(1/2)(max)为VOCl3-ETCA >V5-9-ETCA >V(ocac)-ETCA。结合结晶度、Tg、以及不同序列分布共聚物组成的测定,可推测VOCl3-体系乙丙共聚物具有较长的聚乙烯序列结构,V5-9-体系次之,V(acac)3-体系的乙丙共聚物分子链有更多的无规结构。
English
CRYSTALLIZATION RATE AND SEQUENCE STRUCTURE OF ETHYLENE-PROPYLENE COPOLYMERS
Abstract:
The effects of the catalyst system and composition of ethylene-propylene copolymers on the crystallization rates of the copolymer have been studied by dilatometry. It is shown that for the same catalyst system, the maximum crystallisation rate 1/t(1/2)(max) of the copolymer increased with the increase of the ethylene content in it.The maximum crystallization rates of ethylene-propylene copolymers obtained with various catalyst systems were found in the following order:(VOCl3-) >(V5-0) >(V(acac)3-) The order of 1/t1/2(max) for the catalyst system with addition of an active agent ETCA was:(VOCl3-ETCA) >(V5-9-ETCA) >(V(acac)3-ETCA) The results of the crystallinity and glass transition temperature of the coplymers, as well as the composition of copolymers of differnt sequence suggested that the ethylene-propylene copolymer obtained with VOCl3- had longer PE species and those obtained with V5-9- had shorter PE species. More irregular structure was formed when the copolymer is obtained with V(acac)3-catalyst system.
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Key words:
- Ethylene-propylene copolymer
- / Crystallisation rate
- / Sequence structure
- / Dilatometry
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