Citation:
TANG Guo-Dong, ZHANG Jin-Fang, SONG Ying-Lin, ZHANG Chi, LU Lu-De. Structure and Nonlinear Optical Property of the Cluster Compound V2S6O2Cu6(3-MePy)6[J]. Chinese Journal of Structural Chemistry,
2014, 33(6): 921-927.

Structure and Nonlinear Optical Property of the Cluster Compound V2S6O2Cu6(3-MePy)6
摘要:
A cluster compound V2S6O2Cu6(3-MePy)6 (3-MePy=3-methyl pyridine) has been synthesized by using skiving method and the crystal structure was characterized by X-ray diffraction: space group P1, Z=1, a=9.7278(4), b=10.4180(5), c=11.9230(6)Å, α=108.240(3), β=98.120(2), γ=99.500(2)°, R=0.052 and wR=0.104. The NLO properties were studied by Z-scan technique with 8 ns pulsed laser at 532 nm. The cluster exhibits strong NLO absorptive ability (α2=1.7×10-10 m·W-1) and effective self-focusing performance (n2=1.27×10-18 m2·W-1) in a 1.58×10-4 mol·dm-3 DMF solution.
English
Structure and Nonlinear Optical Property of the Cluster Compound V2S6O2Cu6(3-MePy)6
Abstract:
A cluster compound V2S6O2Cu6(3-MePy)6 (3-MePy=3-methyl pyridine) has been synthesized by using skiving method and the crystal structure was characterized by X-ray diffraction: space group P1, Z=1, a=9.7278(4), b=10.4180(5), c=11.9230(6)Å, α=108.240(3), β=98.120(2), γ=99.500(2)°, R=0.052 and wR=0.104. The NLO properties were studied by Z-scan technique with 8 ns pulsed laser at 532 nm. The cluster exhibits strong NLO absorptive ability (α2=1.7×10-10 m·W-1) and effective self-focusing performance (n2=1.27×10-18 m2·W-1) in a 1.58×10-4 mol·dm-3 DMF solution.
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Key words:
- crystal structure
- / nonlinear optics
- / vanadium cluster
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