Citation: Ma Xiuzhen, Hu Bin. Volumetric Properties of NaCl-KCl-H₂O System and Their Correlation with Pitzer Model[J]. Chemistry, ;2020, 83(5): 459-463. shu

Volumetric Properties of NaCl-KCl-H₂O System and Their Correlation with Pitzer Model

Ma Xiuzhen ,
Hu Bin ^,

Key Laboratory of Comprehensive and Highly Efficient Utilization of Salt Lake Resources, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences; Key Laboratory of Salt Lake Resources Chemistry of Qinghai Province, Xining, 810008

Corresponding author: Hu Bin, hubin@isl.ac.cn
Received Date: 5 November 2019
Accepted Date: 25 December 2019

Figures(3)

The densities of NaCl-KCl aqueous mixture were determined at temperatures from 288.15 to 323.15 K and over a range of composition at ionic strength of 0.1~4 mol·kg^-1. A high precision vibrating-tube densitometer was used in the measurement. The excess volumes of the mixed electrolytes calculated from the experimental data permitted a parameterization of the Pitzer model for mixtures with the entire range of temperatures and compositions covered by this study. In addition, using the Pitzer model, we determined the volume of mixing at constant ionic strength and at 298.15 K.
- Density,
- Pitzer ion-interaction Model,
- Salt lake brine,
- Volume of mixing
1. [1]
  Wang S. J. Salt Lake Res., 2000, 8(4): 44~49.
2. [2]
  Pitzer K. J. Phys. Chem., 1973, 77(2), 268~277.
3. [3]
  Pitzer K. Activity coefficients in electrolyte solutions, second edition, CRC, Ann Arbor, 1991.
4. [4]
  Harvie C, Weare J. Geochim. Cosmochim. Acta, 1980, 44(7): 981~997.
5. [5]
  Krumgalz B. J. Mol. Liq., 2001, 91(1/3): 3~19.
6. [6]
  Lassin A, Andre L, Lach A, et al. Calphad, 2018, 61: 126~139.
7. [7]
  Ruby C, Kawa J. J. Am. Chem. Soc., 1926, 48(5): 1119~1128.
8. [8]
  Wirth H. J. Am. Chem. Soc., 1937, 59(12): 2549~2554.
9. [9]
  Campbell A, Kartzmark E. Can. J. Chem., 1956, 34(5): 672~678.
10. [10]
  Fabuss B, Korosi A, Othmer D. J. Chem. Eng. Data, 1969, 14(2): 192~197.
11. [11]
  Kumar A. J. Chem. Eng. Data, 1988, 33(2): 198~199.
12. [12]
  Zezin D, Driesner T, Sanchez-Valle C. J. Chem. Eng. Data, 2014, 59(3): 736~749.
13. [13]
  Ghafri S, Maitland G, Trusler P. J. Chem. Eng. Data, 2012, 57(4): 1288~1304.
14. [14]
  Dedick E, Hershey J, Sotolongo S, et al. J. Solution. Chem., 1990, 19(4): 353~374.
15. [15]
  Hu B, Hnědkovsky L, Li W, et al. J. Chem. Eng. Data, 2016, 61(4): 1388~1394.
16. [16]
  Krumgalz B, Pogorelskii R, Pitzer K. J. Solution Chem., 1995, 24(10): 1025~1038.
17. [17]
  Krumgalz B, Pogorelskii R, Sokolov A, et al. J. Phys. Chem. Ref. Data, 2000, 29(5): 1123~1140.
18. [18]
  Wagner W, Pruss A. J. Phys. Chem. Ref. Data, 2002, 31(2): 387~535.
19. [19]
  Desnoyer J, Arel M, Perron G, et al. J. Phys. Chem., 1969, 73(10): 3346~3351.
20. [20]
  Lovera J, Hernandez-Luiz F, Galleguillos H. J. Chem. Eng. Data, 2008, 53(12): 2902~2906.
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Volumetric Properties of NaCl-KCl-H2O System and Their Correlation with Pitzer Model

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通讯作者: 陈斌, bchen63@163.com

Volumetric Properties of NaCl-KCl-H₂O System and Their Correlation with Pitzer Model