Citation: Gao Bowen, Su Lei, Zhang Xueji. Fabrication of Manganese Dioxide Nanotube Array through Potassium Permanganate Reduction by Polydopamine Coatings Formed on Zinc Oxide Nanorod Array Template[J]. Chemistry, ;2017, 80(1): 53-58. shu

Fabrication of Manganese Dioxide Nanotube Array through Potassium Permanganate Reduction by Polydopamine Coatings Formed on Zinc Oxide Nanorod Array Template

Gao Bowen ,
Su Lei ^*,, ,
Zhang Xueji ^*,,

Research Center for Bioengineering and Sensing Technology, University of Science and Technology Beijing, Beijing 100083

Corresponding author: Su Lei, sulei@ustb.edu.cn Zhang Xueji, zhangxueji@ustb.edu.cn
Received Date: 17 August 2016
Accepted Date: 10 September 2016

Figures(7)

In this work, manganese dioxide (MnO₂) nanotube arrays are fabricated by using polydopamine coated-zinc oxide nanorod supported on quartz plates as template, followed by potassium permanganate reduction by polydopamine and the ZnO template removal. Characterization results showed that as-fabricated MnO₂ nanotubes have well-defined tube morphology and strongly adhere to the substrate. The formed MnO₂ is amorphous. Polydopamine coated zinc oxide nanostructure as template exhibits several advantages, for example, it possesses diverse surface morphologies, and is easy to be synthesized and removed; the formation of polydopamine is also facile. These advantages might pave the way towards simple and facile fabrication of various MnO₂ nanostructures.
- Manganese dioxide,
- Nanotube array,
- Polydopamine,
- Zinc oxide,
- Template-directed synthesis approach
1. [1]
  M Huang, F Li, F Dong et al. J. Mater. Chem. A, 2015, 3:21380-21423.
2. [2]
  C J Xu, F Y Kang, B H Li et al. J. Mater. Res., 2010, 25(8):1421-1432.
3. [3]
  J Y Cao, X H Li, Y M Wang et al. J. Power Sources, 2015, 293:657-674.
4. [4]
  Y M He, W J Chen, X D Li et al. ACS Nano, 2013, 7(1):174-182.
5. [5]
  P H Yang, X Xiao, Y Z Li et al. ACS Nano, 2013, 7(3):2617-2626.
6. [6]
7. [7]
8. [8]
9. [9]
  Y C Lu, S H Yang. J. Phys. Chem. Lett., 2013, 4:93-99.
10. [10]
  D A Tompsett, M S Islam. Chem. Mater., 2013, 25:2515-2526.
11. [11]
  X H Lu, M H Yu, G M Wang et al. Adv. Mater., 2013, 25:267-272.
12. [12]
  C C Kuo, W J Lan, C H Chen. Nanoscale, 2014, 6:334-341.
13. [13]
  J Y Qu, L Shi, C X He. Carbon, 2014, 66:485-492.
14. [14]
  H Wang, G J Zhao, M Pumera. J. Am. Chem. Soc., 2014, 136:2719-2722.
15. [15]
16. [16]
  B Y Bai, J H Li, J M Hao. Appl. Catal. B:Environ., 2015, 164:241-250.
17. [17]
  L Li, K Scott, E H Yu. J. Power Sources, 2013, 221:1-5.
18. [18]
  H J Huang, Q Chen, M Y He et al. J. Power Sources, 2013, 239:189-195.
19. [19]
  T D Dang, A N Banerjee, M A Cheney et al. Colloid Surf. B, 2013, 106:151-157.
20. [20]
21. [21]
  J J Shan, Y Zhu, S R Zhang et al. J. Phys. Chem. C, 2013, 117:8329-8335.
22. [22]
23. [23]
  B Y Bai, Q Qiao, J H Li et al. Chin. J. Catal., 2016, 37:27-31.
24. [24]
25. [25]
  C C Ji, H Q Ren, S C Yang. RSC Adv., 2015, 5:21978-21987.
26. [26]
  M Q Xue, Z Xie, L S Zhang et al. Nanoscale, 2011, 3:2703-2708.
27. [27]
  Y Wang, J Zhu, J Han et al. Nanotechnology, 2008, 19:1-8.
28. [28]
  C L Xu, S J Bao, L B Kong et al. J. Solid State Chem., 2006, 179:1351-1355.
29. [29]
  X Wang, Y D Li. Chem. Eur. J., 2003, 9(1):300-3006.
30. [30]
  T Gao, M Glerup, F Krumeich et al. J. Phys. Chem. C, 2008, 112:13134-13140.
31. [31]
  F Y Cheng, Y Su, J Liang et al. Chem. Mater., 2010, 22:898-905.
32. [32]
  J W Long, L R Qadir, R M Stroud et al. J. Phys. Chem. B, 2001, 105:8712-8717.
33. [33]
  C Z Wei, H Pang, B Zhang et al. Sci. Rep., 2013, 3:2193-2197.
34. [34]
35. [35]
  M Zhou, X Zhang, J M Wei et al. J. Phys. Chem. C, 2011, 115:1398-1402.
36. [36]
  P Umek, A Gloter, M Pregelj et al. J. Phys. Chem. C, 2009, 113:14798-14803.
37. [37]
  H Q Wang, J Chen, S J Hu et al. RSC Adv., 2015, 5:72495-72499.
38. [38]
  C Z Yuan, L R Hou, L Yang et al. J. Mater. Chem., 2011, 21:16035-16041.
39. [39]
  D Yan, P X Yan, G H Yue et al. Chem. Phys. Lett., 2007, 440:134-138.
40. [40]
  T D Dang, A N Banerjee, S W Joo et al. Ind. Eng. Chem. Res., 2014, 53:9743-9753.
41. [41]
  J Yue, X Gu, X L Jiang et al. Electrochim. Acta, 2015, 182:676-681.
42. [42]
  H Chen, B Zhang, F Li et al. Electrochim. Acta, 2016, 187:488-495.
43. [43]
  Q R Liu, X G Duan, H Q Sun et al. J. Phys. Chem. C, 2016, 120:16871-16878.
44. [44]
  H Q Wang, G F Yang, Q Y Li et al. New J. Chem., 2011, 35:469-475.
45. [45]
  G H An, J I Sohn, H J Ahn. J. Mater. Chem. A, 2016, 4:2049-2054.
46. [46]
  J J Shang, B BXie, Y Li et al. ACS Nano, 2016, 10:5916-5921.
47. [47]
  J Yan, L P Yang, M F Lin et al. Small, 2013, 9(4):596-603.
48. [48]
  Y Wang, P S Ding, C Wang. J. Alloys Compd., 2016, 654:273-279.
49. [49]
  Z X Yang, J Liang, F Y Cheng et al. Micropor. Mesopor. Mater., 2012, 161:40-47.
50. [50]
  J G Wang, Y Yang, Z H Huang et al. Mater. Chem. Phys., 2013, 140:643-650.
51. [51]
  G G Kumar, Z Awan, K S Nahm et al. Biosens. Bioelectron., 2014, 53:528-534.
52. [52]
  W H Guo, T J Liu, P Jiang et al. J. Colloid Interf. Sci., 2015, 437:304-310.
53. [53]
  L Y Chen, J L Kang, Y Hou et al. J. Mater. Chem. A, 2013, 1:9202-9207.
54. [54]
  S M Zhu, Z Y Zhou, D Zhang et al. Micropor. Mesopor. Mater., 2006, 95:257-264.
55. [55]
  X Yang, D G He, X X He et al. Part. Part. Syst. Charact., 2015, 32:205-212.
56. [56]
  Z Y Wang, F P Wang, J H Tu et al. Mater. Lett., 2016, 171:10-13.
57. [57]
  X Z Wang, Y H Xiao, D C Su et al. Electrochim. Acta, 2016, 194:377-384.
58. [58]
  J Zhi, O Reiser, Y F Wang et al. Nanoscale, 2016, 8:11976-11983.
59. [59]
  Y L Xi, G D Wei, X L Liu et al. Chem. Eng. J., 2016, 290:361-370.
60. [60]
  S H S Zein, L C Yeoh, S P Chai et al. J. Mater. Process. Technol., 2007, 190:402-405.
61. [61]
  Q Wang, J Yan, Y B Wang et al. Carbon, 2013, 52:209-218.
62. [62]
  S Hong, S Lee, U Paik. Electrochim. Acta, 2014, 141:39-44.
63. [63]
  H Xia, J K Feng, H L Wang et al. J. Power Sources, 2010, 195:4410-4413.
64. [64]
  Y G Huang, X H Zhang, X B Chen et al. Int. J. Hydrogen Energy, 2015, 40:14331-14337.
65. [65]
  Y Liu, J Xu, H G Li et al. J. Mater. Chem. A, 2015, 3:11543-11553.
66. [66]
  Q Li, Z L Wang, G R Li et al. Nano Lett., 2012, 12:3803-3807.
67. [67]
  J H Han, Z F Liu, K Y Guo et al. Appl. Catal. B:Environ., 2015, 163:179-188.
68. [68]
  W Gong, W S Chen, J P He et al. Carbon, 2015, 83:275-281.
69. [69]
  D Yan, P C Xu, Q Xiang et al. J. Mater. Chem. A, 2016, 4:3487-3493.
70. [70]
  B W Gao, L Su, X J Zhang et al. J. Phys. Chem. B, 2014, 118:12781-12787.
71. [71]
  Y Ma, S G Wang, M H Fan et al. J. Hazard. Mater., 2009, 168:1140-1146.
72. [72]
  P Mahamallik, S Saha, A Pal. Chem. Eng. J., 2015, 276:155-165.
73. [73]
  M Q Wu, L P Zhang, J H Gao et al. J. Electrochem. Soc., 2008, 155(5):355-360.
74. [74]
  S Ashoka, P Chithaiah, C N Tharamani et al. J. Exp. Nanosci., 2010, 5(4):285-293.
75. [75]
  W Q Ma, Q Q Shi, H H Nan et al. RSC Adv., 2015, 5:39864-39869.
76. [76]
  J H Yang, J H Zheng, H J Zhai et al. J. Alloys Compd., 2009, 475:741-744.
77. [77]
  Y Surace, M Simões, S Pokrant et al. J. Electroanal. Chem., 2016, 766:44-51.
78. [78]
  M Musil, B Choi, A Tsutsumi. J. Electrochem. Soc., 2015, 162(10):2058-2065.
79. [79]
  J B Jia, P Y Zhang, L Chen. Appl. Catal. B, 2016, 189:210-218.
80. [80]
81. [81]
  H Lee, S M Dellatore, W M Miller et al. Science, 2007, 318:426-430.
82. [82]
  Y Zhao, P Jiang, S S Xie. J. Power Sources, 2013, 239:393-398.
83. [83]
  K Govender, D S Boyle, P B Kenway et al. J. Mater. Chem., 2004, 14:2575-2591.
84. [84]
  M Guo, P Diao, S Cai. J. Solid State Chem., 2005, 178:1864-1873.
85. [85]
  B Yin, Y Qiu, H Q Zhang. RSC Adv., 2016, 6:48319-48323.
86. [86]
  V Ball, D Del Frari, M Michel et al. BioNanoSci., 2012, 2:16-34.
87. [87]
  N F D Vecchia, R Avolio, M E Errico et al. Adv. Funct. Mater., 2013, 23:1331-1340.
88. [88]
  J Liebscher, H A Scheidt, C Filip et al. Langmuir, 2013, 29:10539-10548.
89. [89]
  Y Liu, K Ai, L Lu. Chem. Rev., 2014, 114(9):5057-5115.
1. [1]
  Xinxin Dai , Di Lan , Xingliang Chen , Xingwei Wang , Guangbin Ji . One pot green synthesis and electromagnetic wave absorption performance of manganese dioxide@nitrogen-doped carbon@NiFe₂O₄ hybrids. Acta Physico-Chimica Sinica, 2026, 42(8): 100302-0. doi: 10.1016/j.actphy.2026.100302
2. [2]
  Zengsheng LI , Peijie LI , Jinhe HUANG , Yanbing ZHANG , Xiaobing WANG , Qiao FENG , Hua SUN , Kai LIU , Xiaoyan LI , Han MA , Ziyi XUAN , Xiangyang JING , Jiasen WANG , Haibo REN . Response surface methodology optimization of the preparation and performance of MnO_x/polydopamine@carbon nanotubes denitration catalyst. Chinese Journal of Inorganic Chemistry, 2026, 42(10): 2109-2118. doi: 10.11862/CJIC.20260145
3. [3]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
4. [4]
  Ruifeng CHEN , Chao XU , Jianting JIANG , Tianshe YANG . Gold nanorod/zinc oxide/mesoporous silica nanoplatform: A triple-modal platform for synergistic anticancer therapy. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2272-2282. doi: 10.11862/CJIC.20250117
5. [5]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
6. [6]
  Zhen Li , Sujuan Zhang , Zhongliao Wang , Jinfeng Zhang , Gaoli Chen , Shifu Chen . Rational design of S-scheme CdS/MnO₂ heterojunctions for high-value photothermal synergistic catalytic oxidation of toluene. Acta Physico-Chimica Sinica, 2026, 42(4): 100179-0. doi: 10.1016/j.actphy.2025.100179
7. [7]
  Qingtao CHEN , Xiangdong SHI , Xianghai RAO , Jiong LI , Xiaoyun QIN , Yiwen GUAN , Binyan ZOU , Guixia LIU , Fenghua CHEN . Employing polydopamine as an electron bridge to construct an S-scheme heterojunction and flexible film for highly efficient photocatalytic degradation of water pollutants. Chinese Journal of Inorganic Chemistry, 2026, 42(4): 747-759. doi: 10.11862/CJIC.20250286
8. [8]
  Xinyue Xia , Yingfeng Liu , Zilin Liu , Yuxi Wu , Yibo Guo , Yanni Long , Xiaochuan Zou . 哪吒“藕身重塑”记. University Chemistry, 2026, 41(9): 235-243. doi: 10.12461/PKU.DXHX202507016
9. [9]
  Xinmeng Huang , Haoran Zhang , Mengxin Liu , Ying Miao , Zhenxi Yu , Qi Wu , Lei Pan . A densified conductive network of carbon nanotube-bridged vertical ZnO arrays for enhanced electromagnetic interference shielding, mechanical, and thermal properties of carbon fiber/polymer composites. Acta Physico-Chimica Sinica, 2026, 42(10): 100293-0. doi: 10.1016/j.actphy.2026.100293
10. [10]
  Bowen Liu , Jianjun Zhang , Han Li , Bei Cheng , Chuanbiao Bie . MOF-derived ZnO/PANI S-scheme heterojunction for efficient photocatalytic phenol mineralization coupled with H₂O₂ generation. Acta Physico-Chimica Sinica, 2025, 41(10): 100121-0. doi: 10.1016/j.actphy.2025.100121
11. [11]
  Yucheng Shan , Liming Xu , Peng Sun , Zhijing Zhu , Chenglong Wang , Jinliang Li , Guang Yang , Likun Pan . A data-driven approach for rapid revealing of metal doping in MnO₂ cathodes for high-performance aqueous zinc-ion batteries. Acta Physico-Chimica Sinica, 2026, 42(7): 100232-. doi: 10.1016/j.actphy.2025.100232
12. [12]
  Yuchen ZHANG , Jingliang LIU , Xiaobo WANG , Jingjing CAO , Jingya SUN . Degradation of tannic acid on activation of peroxymonosulfate mediated by β-MnO₂. Chinese Journal of Inorganic Chemistry, 2026, 42(7): 1505-1512. doi: 10.11862/CJIC.20260003
13. [13]
  Yu Wang , Shoulei Zhang , Tianming Lv , Yan Su , Xianyu Liu , Fuping Tian , Changgong Meng . Introduce a Comprehensive Inorganic Synthesis Experiment: Synthesis of Nano Zinc Oxide via Microemulsion Using Waste Soybean Oil. University Chemistry, 2024, 39(7): 316-321. doi: 10.3866/PKU.DXHX202311035
14. [14]
  Xiaolong Li , Shiqi Zhong , Xiangfeng Wei , Zhiqiang Liu , Pan Zhan , Jiehua Liu . Carbon Dioxide: From the Past to the Future. University Chemistry, 2026, 41(2): 242-247. doi: 10.12461/PKU.DXHX202503013
15. [15]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
16. [16]
  Bizhu Shao , Huijun Dong , Yunnan Gong , Jianhua Mei , Fengshi Cai , Jinbiao Liu , Dichang Zhong , Tongbu Lu . Metal-Organic Framework-Derived Nickel Nanoparticles for Efficient CO₂ Electroreduction in Wide Potential Windows. Acta Physico-Chimica Sinica, 2024, 40(4): 2305026-0. doi: 10.3866/PKU.WHXB202305026
17. [17]
  Chunyue Fang , Xiaoxuan Tan , Chunhong Wang , Yang He , Xiaoyuan Pei , Yu Zhang , Sarani binti Zakaria , Guangwei Fu , Jiangang Wang , Li Chen , Kun Liu , Ting Xu , Chuanling Si . Janus liquid metal@Mxene/Fe₃O₄ nanofiber membranes with polydopamine-confined liquid metal for electromagnetic interference shielding and infrared control. Acta Physico-Chimica Sinica, 2026, 42(10): 100281-0. doi: 10.1016/j.actphy.2026.100281
18. [18]
  Shuhong Xiang , Lv Yang , Yingsheng Xu , Guoxin Cao , Hongjian Zhou . Selective electrosorption of Cs(Ⅰ) from high-salinity radioactive wastewater using CNT-interspersed potassium zinc ferrocyanide electrodes. Acta Physico-Chimica Sinica, 2025, 41(9): 100097-0. doi: 10.1016/j.actphy.2025.100097
19. [19]
  Chen Pu , Daijie Deng , Henan Li , Li Xu . Fe_0.64Ni_0.36@Fe₃NiN Core-Shell Nanostructure Encapsulated in N-Doped Carbon Nanotubes for Rechargeable Zinc-Air Batteries with Ultralong Cycle Stability. Acta Physico-Chimica Sinica, 2024, 40(2): 2304021-0. doi: 10.3866/PKU.WHXB202304021
20. [20]
  Yucai Zhang , Jun Jiang . Electrochemical Carbon Dioxide Reduction to Ethylene. University Chemistry, 2026, 41(2): 190-196. doi: 10.12461/PKU.DXHX202503006

Get Citation

PDF

XML

Metrics

PDF Downloads(18)
Abstract views(5447)
HTML views(897)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142