Citation: Chuan Pu LIU, Xiang Yang LI, Jing Zhong GUO, Yue Shu GU, Xue Chu LI, Guan Lin SHEN, Hong CHEN. The Effect of the CO(a₃П) Vibrational Population on the CO(a₃П)+NO(X₃П) Energy Transfer Reaction[J]. Chinese Chemical Letters, ;1996, 7(9): 855-858. shu

The Effect of the CO(a₃П) Vibrational Population on the CO(a₃П)+NO(X₃П) Energy Transfer Reaction

a Department of Chemistry, Shandong University, Jinan 250100;
b State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics CAS, P, O, Box 110, Dalian 116023

Received Date: 11 March 1995

Fund Project: This work was supported by the National Natural Science Foundation of China.

The improved beam sources CO (a, v≤4) and CO (a, v≤3) are produced in a beam-gas experiment by collision of CO₂ with He (2² S) and Ar (³P_{0, 2}) respectively. The energy transfer reaction of CO (a) with NO (x) mainly give NO (A, v). The vibrational distribution of CO (a) has a considerable effect on that of NO (A, v) and the vibrational distributions of NO (A, v) follow the energy gap law and the Franck-Condon (F-C) principle.
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