Citation: Quan Ling SUO, Xing Ming LIU, Yuan Qi YIN, Dao Sen JIN, Shu Ben LI. STRUCTURAL EVIDENCES OF Ru (H)₂(H₂) (PPh₃)₃ AT LOW TEMPERATURE[J]. Chinese Chemical Letters, ;1993, 4(7): 653-656. shu

STRUCTURAL EVIDENCES OF Ru (H)₂(H₂) (PPh₃)₃ AT LOW TEMPERATURE

Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, 730000

Received Date: 2 March 1993

Fund Project: This project is supported by the NNSFC grant.

FTIR spectrum at liquid nitrogen temperature and ¹H NMR of air-sensitive polyhydride Ru(H)₂(H₂)(PPh₃)₃ have been measured for the first time.It is found that a fluxional process happens at room temperature, but the structure of Ru(H)₂(H₂)(PPh₃)₃ with non-equivalent hydrogens is discernible at low temperature.
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