Home

Citation: Liu Yuchen, Wang Yi, Liu Yanxin, Gao Ming. Structural Analysis of Bromonium Ion[J]. Chemistry, ;2019, 82(3): 284-287, 283. shu

Structural Analysis of Bromonium Ion

Liu Yuchen ^1, ,
Wang Yi ² ,
Liu Yanxin ¹ ,
Gao Ming ¹

1.
Department of Applied Chemistry, School of Science, Northeast Agricultural University, Harbin 150036
2.
The NO.5 Middle School of Shenyang, Shenyang 110044

Received Date: 14 September 2018
Accepted Date: 11 October 2018

Figures(8)

The bromonium ion is a cyclic intermediate in the addition of olefin and bromine. A detailed analysis on its structure will be greatly helpful not only in understanding the addition process of different olefins and bromine but also in predicting addition products. At present, there is no detailed introduction about the structure of brominium ions in the textbooks at home and abroad. As an appropriate supplement to the textbooks of organic chemistry, this paper summarized the hybridization modes of each atom and the charge distribution of atoms in three membered ring of the bromonium ion, with the subsequent nucleophilic substitution process also included.
- Bromonium ions,
- Structure,
- Hybridization
1. [1]
  T P Hamilton, H F Schaefer. J. Am. Chem. Soc., 1990, 112(23):8260~8265.
2. [2]
3. [3]
  M Jones, S A Fleming. Organic Chemistry. New York:WW Norton & Company, Inc. 2010.
4. [4]
  J Strating, J H Wieringa, H Wynberg. Chem. Commun., 1969, 16:907~908.
5. [5]
  G A Olah, P W Westerman, E G Melby et al. Chem. Commun., 1974:96(11):3565~3573.
6. [6]
  B Galland, E M Evleth, M F Ruasse. Chem. Commun., 1990, 13:898~900.
7. [7]
  S D Ittel, J A Ibers. Adv. Organomet. Chem., 1976, 14:33~61.
8. [8]
  H Slebocka-Tilk, R G Ball, R S Brown. J. Am. Soc. Chem., 1985,107(15):450~4508.
9. [9]
  R Gedye, R S Brown, H Slebocka-Tilk et al. J. Am. Soc. Chem.,1984, 106(16):4515~4521.
10. [10]
1. [1]
  Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au₁₁(dppf)₄Cl₂ nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047
2. [2]
  Xiao SANG , Qi LIU , Jianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158
3. [3]
  Qiuyu Ming , Huijun Jiang , Zhihao Zhang . A Sightseeing Tour of Folic Acid Processing Plant. University Chemistry, 2024, 39(9): 11-15. doi: 10.12461/PKU.DXHX202404092
4. [4]
  Zhiwen HUANG , Qi LIU , Jianping LANG . W/Cu/S cluster-based supramolecular macrocycles and their third-order nonlinear optical responses. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 79-87. doi: 10.11862/CJIC.20240184
5. [5]
  Ke Zhao , Zhen Liu , Luyao Liu , Changyuan Yu , Jingshun Pan , Xuguang Huang . Functionalized Reflective Structure Fiber-Optic Interferometric Sensor for Trace Detection of Lead Ions. Acta Physico-Chimica Sinica, 2024, 40(4): 2304029-0. doi: 10.3866/PKU.WHXB202304029
6. [6]
  Maitri Bhattacharjee , Rekha Boruah Smriti , R. N. Dutta Purkayastha , Waldemar Maniukiewicz , Shubhamoy Chowdhury , Debasish Maiti , Tamanna Akhtar . Synthesis, structural characterization, bio-activity, and density functional theory calculation on Cu(Ⅱ) complexes with hydrazone-based Schiff base ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1409-1422. doi: 10.11862/CJIC.20240007
7. [7]
  Xufeng LIU , Shaojie WANG , Peihua ZHAO . Ligand substitution of diiron hexacarbonyl complex with aminodiphosphine to prepare diiron aminophosphine complexes relevant to [FeFe]-hydrogenases. Chinese Journal of Inorganic Chemistry, 2025, 41(9): 1851-1858. doi: 10.11862/CJIC.20250131
8. [8]
  Wanting CHEN , Chufei MIAO , Yan LIU , Bobi ZHENG , Xiaoyu ZHENG , Han XU , Jumei TIAN . Syntheses, characterization, and luminescence properties of Yb(Ⅲ)-based one-dimensional chain coordination polymer. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1672-1680. doi: 10.11862/CJIC.20250013
9. [9]
  Xian-Wei Lv , Xinyuan Ding , Jiaxing Gong , Xuhuan Yan , Dayong Huang , Jianxin Geng , Zhong-Yong Yuan . Research progress on orbital hybridization in photocatalysis and electrocatalysis. Acta Physico-Chimica Sinica, 2026, 42(2): 100151-0. doi: 10.1016/j.actphy.2025.100151
10. [10]
  Wenyan Dan , Weijie Li , Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, 2024, 39(3): 63-69. doi: 10.3866/PKU.DXHX202302060
11. [11]
  Yanxin Wang , Hongjuan Wang , Yuren Shi , Yunxia Yang . Application of Python for Visualizing in Structural Chemistry Teaching. University Chemistry, 2024, 39(3): 108-117. doi: 10.3866/PKU.DXHX202306005
12. [12]
  Mengyang LI , Hao XU , Zhonghao NIU , Chunhua GONG , Weihui ZHONG , Jingli XIE . Highly effective catalytic synthesis of β-amino alcohols by using viologen-polyoxometalate hybrid materials. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1294-1300. doi: 10.11862/CJIC.20250080
13. [13]
  Xiangyu CHEN , Zhenzhen MIAO , Ligang XU , Guangbao WU , Zhuang LIU , Wenzhen LÜ , Runfeng CHEN . Research progress on low-dimensional organic-inorganic hybrid metal halide optoelectronic materials. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2201-2217. doi: 10.11862/CJIC.20250056
14. [14]
  Xuyang Wang , Jiapei Zhang , Lirui Zhao , Xiaowen Xu , Guizheng Zou , Bin Zhang . Theoretical Study on the Structure and Stability of Copper-Ammonia Coordination Ions. University Chemistry, 2024, 39(3): 384-389. doi: 10.3866/PKU.DXHX202309065
15. [15]
  Fan Yang , Zheng Liu , Da Wang , KwunNam Hui , Yelong Zhang , Zhangquan Peng . Preparation and Properties of P-Bi₂Te₃/MXene Superstructure-based Anode for Potassium-Ion Battery. Acta Physico-Chimica Sinica, 2024, 40(2): 2303006-0. doi: 10.3866/PKU.WHXB202303006
16. [16]
  Yu Guo , Zhiwei Huang , Yuqing Hu , Junzhe Li , Jie Xu . Recent Advances in Iron-based Heterostructure Anode Materials for Sodium Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(3): 100022-0. doi: 10.3866/PKU.WHXB202311015
17. [17]
  Wen Tang , Luyu Sui , Qian Chen , Jun Shao , Xinwen Peng , Jianwen Jiang , Shuiliang Chen . Project-based Teaching of “the Condensed State of Polymers”: Unveiling the Lithium-Ion Battery Separator. University Chemistry, 2025, 40(11): 115-126. doi: 10.12461/PKU.DXHX202412108
18. [18]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
19. [19]
  Yuqiao Zhou , Weidi Cao , Shunxi Dong , Lili Lin , Xiaohua Liu . Study on the Teaching Reformation of Practical X-ray Crystallography. University Chemistry, 2024, 39(3): 23-28. doi: 10.3866/PKU.DXHX202303003
20. [20]
  Lijun Yang . Thoughts and Practices on Enhancing Students’ Comprehension through Visualized Instruction of Structural Chemistry. University Chemistry, 2025, 40(10): 295-302. doi: 10.12461/PKU.DXHX202411048

Get Citation

PDF

XML

Metrics

PDF Downloads(60)
Abstract views(10177)
HTML views(3332)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return