Citation: ZHAN Hao, LIN Jun-heng, HUANG Yan-qin, YIN Xiu-li, LIU Hua-cai, YUAN Hong-you, WU Chuang-zhi. Evolution of nitrogen functionalities and their relation to NO_x precursors during pyrolysis of antibiotic mycelia wastes[J]. Journal of Fuel Chemistry and Technology, ;2017, 45(10): 1219-1229. shu

Evolution of nitrogen functionalities and their relation to NO_x precursors during pyrolysis of antibiotic mycelia wastes

1.
Key Laboratory of Renewable Energy, CAS, Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: WU Chuang-zhi, wucz@ms.giec.ac.cn
Received Date: 25 May 2017
Revised Date: 13 August 2017

Fund Project: The project was supported by the National Natural Science Foundation of China 51676195The project was supported by the National Natural Science Foundation of China 51661145022The project was supported by the National Natural Science Foundation of China (51676195, 51661145022)

Figures(8)

On the basis of rapid pyrolysis of two antibiotic mycelial wastes (AMWs), viz., penicillin mycelia waste (PMW) and terramycinmycelial waste (TMW), in a horizontal tubular quartz reactor, evolution of nitrogen functionalities and their relation to NO_x precursors were investigated with the help of XPS and chemical absorption-spectrophotometry methods.The results indicate that inorganic-N (N-IN) and amide-N/amine-N/amino-N (N-A) are two kinds of nitrogen functionalities in the raw AMWs samples, determining the predominance of NH₃-N among NO_x precursors. N-A is found to be the main one with the proportion of 81.1% and 59.0% for PMW and TMW, respectively. At low temperatures, the decomposition of N-IN and the conversion of N-A mainly occur at 150-250℃ and 250-450℃, respectively, which are two routes for most NH₃-N with yields of 20.9% (PMW) and 25.6% (TMW). While HCN-N is produced with a small amount less than 2%, having no relationship with the characteristics of nitrogen functionalities in fuels. Besides, pyridinic-N (N-6) and pyrrolic-N (N-5) are also formed and then converted with peak values at 350-400℃. At high temperatures, the conversion of N-6 and N-5 is prevailing, leading to the basically equal increments on NH₃-N and HCN-N. Simultaneously, a minor amount of more stable quaternary nitrogen (N-Q) and N-oxide (N-X) is produced. Typically, due to the rapid decomposition of N-IN and labile N-A at low-temperature pyrolysis, nitrogen removal can reach up to 40% while energy loss can be controlled within 25% when pyrolyzing at 250-300℃. As a result, low-temperature pyrolysis could be an effective method for nitrogen removal whereas preserving the energy in AMWs.
- AMWs,
- nitrogen functionalities,
- NO_x precursors,
- low-temperature pyrolysis,
- nitrogen removal
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沈阳化工大学材料科学与工程学院沈阳 110142

Evolution of nitrogen functionalities and their relation to NOx precursors during pyrolysis of antibiotic mycelia wastes

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通讯作者: 陈斌, bchen63@163.com

Evolution of nitrogen functionalities and their relation to NO_x precursors during pyrolysis of antibiotic mycelia wastes