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Citation: WANG Xiao-guang, LIU Dai, CHEN Shao-yun, LIU Yang, ZHANG Yong-chun. Performance of pentaethylenehexamine modified MIL-101(Cr) metal-organic framework in CO2 adsorption[J]. Journal of Fuel Chemistry and Technology, ;2017, 45(4): 484-490. shu

Performance of pentaethylenehexamine modified MIL-101(Cr) metal-organic framework in CO2 adsorption

  • Dalian University of Technology, Institute of Chemical Engineering, State Key Laboratory of Fine Chemicals, Dalian 116023, China

  • Corresponding author: ZHANG Yong-chun, zalidy5518@vip.sina.com
  • Received Date: 6 January 2017
    Revised Date: 13 March 2017

Figures(11)

  • The metal-organic framework MIL-101(Cr) was synthesized via hydrothermal process and then modified with pentaethylenehexamine (PEHA) through refluxing in ethanol. Various measures such as SEM, XRD, N2 sorption, Elemental analysis and FT-IR were used to characterize the structure, morphology and properties of PEHA-grafted MIL-101(Cr). Meanwhile, the performance of PEHA-grafted MIL-101(Cr) in CO2 adsorption was investigated under 25℃. The results illustrate that the loading of PEHA in MIL-101(Cr) can conspicuously enhance the CO2 adsorption capacity. PEHA-grafted MIL-101(Cr) with a PEHA loading of 0.24 mL exhibits the highest capacity for CO2 adsorption; the adsorption capacity reaches 58.944 mg/g at 25℃ and atmospheric pressure, which is 33% higher than that of the unmodified MIL-101(Cr) (44.208 mg/g). In addition, the CO2 adsorption capacities on both MIL-101(Cr) and PEHA-MIL-101(Cr) are greatly enhanced by increasing pressure, reaching 1 147.59 and 1 256.74 mg/g at 1.1 MPa, respectively. These results suggest that PEHA-modified MIL-101(Cr) could be a good candidate adsorbent for CO2 capture at high pressure.
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