Citation: Qing Yun CHEN, Ming Fang CHEN. PENTAFLUOROBENZENESULFONYL BROMIDE AND ITS REACTIONS[J]. Chinese Chemical Letters, ;1991, 3(8): 597-600. shu

PENTAFLUOROBENZENESULFONYL BROMIDE AND ITS REACTIONS

Shanghai Institute of Organic Chemistry Chinese Academy of Sciences Shanghai 200032

Received Date: 8 June 1991

Pentafluorobenzenesulfonyl bromide was synthesized by the reaction of pentafluorophenylmagnesium chloride with sulphur dioxide followed by bromine oxidation. The sulfonyl bromide reacted with polyfluorophenoxide to form polyfluorophenyl pentafluorobenzenesulfonates. Photolysis of pentafluorobenze-nesulfonyl bromide gave bis(pentafluorobenzene)sulfone and decafluorodiphenyl.
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