{"extraData":"\"66578,17,13,19934,,\"","message":"成功","title":"成功","valid":"true"} Highly Stereoselective Synthesis of (<i>E</i>, <i>E</i>)-3,7-Dimethyl-2,6-decadiene-1, 10-diol

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Citation: Zuo Sheng LIU, Jiong LAN, Li Zeng PENG, Yu Lin LI, Ya Cheng XING, Wen CEN. Highly Stereoselective Synthesis of (E, E)-3,7-Dimethyl-2,6-decadiene-1, 10-diol[J]. Chinese Chemical Letters, ;1999, 10(7): 547-548. shu

Highly Stereoselective Synthesis of (E, E)-3,7-Dimethyl-2,6-decadiene-1, 10-diol

1.
National Laboratory of Applied Organic Chemistry and Institute of Organic Chemistry, Lanzhou University Lanzhou 730000;
2.
Department of Chemistry, Qingdao University, Qingdao 266071

Received Date: 29 December 1998

Fund Project: This work was financially supported by the National Natural Science Foundation of China (Grant No. 29672015)

A total synthesis of (E,E)-3,7-dimethyl-2,6-decadiene-1,10-diol, using 1,3-transfor-mation of 2. 3-epoxy alcohol and Claisen rearrangement of allyl vinyl ether as key steps. is described.
- 2,3-Epoxy alcohol,
- 1,3-transformation,
- Claisen rearrangement,
- synthesis
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