Citation: Yu Cai CAO, Xuan Zhen JIANG. Novel Catalytic Hydrodechlorination of CCl₂F₂ over Supported PdCl₂-(n-C₄H₉)₄N⁺Cl^- Molten salts[J]. Chinese Chemical Letters, ;2001, 12(6): 533-536. shu

Novel Catalytic Hydrodechlorination of CCl₂F₂ over Supported PdCl₂-(n-C₄H₉)₄N⁺Cl^- Molten salts

Department of Chemistry, Zhejiang University, Hangzhou 310027

Received Date: 18 September 2000

A novel supported liquid phase film catalyst:Supported PdCl₂-(n-C₄H₉)₄N⁺Cl^- molten salts was found to be an effective catalyst with good stability for selective hydrodechlorination of CCl₂F₂ (CFC-12) to its alternatives CH₂F₂ and CHClF₂. Addition of CoCl₂, GaCl₃ and CuCl₂ to PdCl₂-(n-C₄H₉)₄N⁺Cl^- modifies the catalytic performance of supported molten salts.
- Liquid film catalyst,
- palladium chloride,
- tetrabutylammonium chloride,
- molten salts,
- CFC-12 hydrodechlorination,
- HFC-32,
- HCFC-22.
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