Citation: Hu Yangyang, Zeng Xianghua, Gong Chunhua, Xin Li, Zhang Jiaqi, Zhang Junyong, Xie Jingli. Synthesis, Structure and Photocatalytic Property of [Mo₆O₁₉]^2- Polyoxometalate with Phosphonium Cation[J]. Chemistry, ;2017, 80(7): 651-655. shu

Synthesis, Structure and Photocatalytic Property of [Mo₆O₁₉]^2- Polyoxometalate with Phosphonium Cation

College of Biological, Chemical Sciences and Engineering, Jiaxing University, Jiaxing 314001

Corresponding author: Zeng Xianghua, xianghuazeng@mail.zjxu.edu.cn Xie Jingli, jlxie@mail.zjxu.edu.cn
Received Date: 2 November 2016
Accepted Date: 4 February 2017

Figures(9)

A polyoxometalate compound [n-C₅H₁₀Ph₃P]₂[Mo₆O₁₉] was synthesized by the reaction of n-C₅H₁₀Ph₃PI and (NH₄)₆Mo₇O₂₄·7H₂O at ambient condition. This compound was characterized by single crystal X-ray diffraction, UV-Vis spectrum, IR spectrum, TGA and electrochemistry analysis. The polyoxometalate compound contains two n-C₅H₁₀Ph₃P⁺ cations. There were hydrogen bonding interactions between terminal oxygen atoms of [Mo₆O₁₉]^2- anions and phosphonium cations, and consequently one dimensional chain was formed. Three dimensional structures were constructed by the π-π stacking between the phenyl rings of the cationic phosphonium. Additionally, its photocatalytic property for the degradation of methylene blue (MB) was also investigated.
- Polyoxometalate,
- Phosphonium cation,
- Crystal structure,
- Photocatalytic,
- Methylene blue
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Synthesis, Structure and Photocatalytic Property of [Mo6O19]2- Polyoxometalate with Phosphonium Cation

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Synthesis, Structure and Photocatalytic Property of [Mo₆O₁₉]^2- Polyoxometalate with Phosphonium Cation