Citation: Chao CHE, Zhong Ning ZHANG, Gui Lan HUANG, Xin Xing WANG, Zhao Hai QIN. Using the Chiral Organophosphorus Derivatizing Agents for Determination of the Enantiomeric Composition of Chiral Carboxylic Acids by ³¹PNMR Spectroscopy[J]. Chinese Chemical Letters, ;2004, 15(6): 675-678. shu

Using the Chiral Organophosphorus Derivatizing Agents for Determination of the Enantiomeric Composition of Chiral Carboxylic Acids by ³¹PNMR Spectroscopy

1.
State Key Laboratory of Integrated Management of Insects and Rodents, Institute of zoology, ChineseAcadamy of Sciences, Beijing 100080;
2.
Graduate School of the Chinese Academy of Sciences, Beijing 100039;
3.
The Sixth Research Center, Institute of Chemical Defence, Beijing 102205;
4.
Department of Applied Chemistry, China Agricultural University, Beijing 100094

Received Date: 26 May 2003

The use of chiral organophosphorus derivatizing agents prepared in situ from chiral tartrate or chiral diamine for the ³¹PNMR determination of the enantiomeric composition of chiral carboxylic acids is described. The method is accurate, reliable and convenient.
- Chiral tartrate,
- chiral diamine,
- enantiomeric composition determination,
- ³¹PNMR,
- carboxylic acids
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