Citation: YANG Wen-shen, LANG Lin, YIN Xiu-li, WU Chuang-zhi. Preparation and H₂S/CH₄ separation performance of MFI type zeolite membrane[J]. Journal of Fuel Chemistry and Technology, ;2018, 46(7): 891-896. shu

Preparation and H₂S/CH₄ separation performance of MFI type zeolite membrane

Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, CAS Key Laboratory of Renewable Energy, Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development, Guangzhou 510640, China

Corresponding author: YIN Xiu-li, xlyin@ms.giec.ac.cn
Received Date: 23 January 2018
Revised Date: 1 May 2018

Fund Project: The project was supported by the National Key R & D Program of China (2016YFE0203300), the Guangdong Natural Science Foundation (2017B030308002) and Science and Technology Program of Guangzhou (201707010242)the Guangdong Natural Science Foundation 2017B030308002Science and Technology Program of Guangzhou 201707010242the National Key R & D Program of China 2016YFE0203300

Figures(4)

The MFI (ZSM-5 and silicate-1) membranes with porous α-Al₂O₃ substrates were synthesized by secondary growth method. The results of scanning electron microscopy (SEM) and X-ray diffraction (XRD) indicate that the membranes with 5 μm thickness are composed of well-intergrown MFI crystals, which completely covers on the α-Al₂O₃ substrates in random orientation. The gas permeation measurements reveal that the resulting membranes are of high quality with few non-zeolitic pores. In addition, the separation properties of H₂S/CH₄ through the synthesized MFI membranes were investigated. Under the osmotic pressure of 0.3 and 0.5 MPa, the separation factors of H₂S/CH₄ by silicate-1 zeolite membrane are 1.99 and 4.44, and the separation factors of CH₄/H₂S by ZSM-5 zeolite membrane are 6.71 and 12.85, respectively.
- MFI zeolite membrane,
- H₂S/CH₄ separation,
- secondary growth method
1. [1]
  LIN Y S, KUMAKIRI I, NAIR B N, ALSYOURI H. Microporous inorganic membranes[J]. Sep Purif Methods, 2002,31(2):229-379. doi: 10.1081/SPM-120017009
2. [2]
  CARO J, NOACK M, KÖLSCH P, SCHÄFER R. Zealite membrane-state of their development and perspective[J]. Microporous Mesoporous Mater, 2000,38(1):3-24. doi: 10.1016/S1387-1811(99)00295-4
3. [3]
  SNYDER M A, TSAPATSIS M. Hierarchical nanomanufacturing:from shaped zeolite nanoparticles to high performance separation membranes[J]. Angew Chem Int Ed, 2007,46(40):7560-7573. doi: 10.1002/(ISSN)1521-3773
4. [4]
  XIA S X, PENG Y, LU H B, WANG Z B. The influence of nanoseeds on the pervaporation performance of MFI-type zeolite membranes on hollow fibers[J]. Microporous Mesoporous Mater, 2016,222(1):128-137.
5. [5]
  UENO K, NEGISHI H, OKUNO T, SAITO T, TAWARAYAMA H, ISHIKAWA S, MIYAMOTO M, UEMIYA S, SAWADA Y, OUMI Y. A simple secondary growth method for the preparation of silicalite-1 membrane on a tubular silica support via gel-free steam-assisted conversion[J]. J Membr Sci, 2017,542(15):150-158.
6. [6]
  JIN S L, LEE Y J, TAE E L, YONG S P, YOON K B. Synthesis of zeolite as ordered multicrystal arrays[J]. Science, 2003,301(5634):818-821. doi: 10.1126/science.1086441
7. [7]
  YAN Y, AND Z W. Controlling crystal orientation in zeolite MFI thin films by direct in situ crystallization[J]. Chem Mater, 2001,13(3):1101-1107. doi: 10.1021/cm000849e
8. [8]
  HEDLUNDA J, NOACKB M, KÖLSCH P, CREASERA D, CAROB J, STERTEA J. ZSM-5 membranes synthesized without organic templates using a seeding technique[J]. J Membr Sci, 1999,159(1/2):263-273.
9. [9]
  LAI R, GAVALAS G R. ZSM-5 membrane synthesis with organic-free mixtures[J]. Microporous Mesoporous Mater, 2000,38(2/3):239-245.
10. [10]
  UENO K, NEGISHI H, OKUNO T, SAITO T, TAWARAYAMA H, ISHIKAWA S, MIYAMOTO M, UEMIYA S, SAWADA Y, OUMI Y. High-performance silicalite-1 membranes on porous tubular silica supports for separation of ethanol/water mixtures[J]. Sep Purif Technol, 2017,187(31):343-354.
11. [11]
  LANG L, LIU X F, ZHANG B Q. Synthesis and characterization of h0h-oriented silicalite-1 films on α-Al₂O₃substrates[J]. Appl Surf Sci, 2008,254(8):2353-2358. doi: 10.1016/j.apsusc.2007.09.031
12. [12]
  ARRUEB M, CORONAS J, MENÉNDEZ M, SANTAMARIA J. Separation of hydrocarbons from natural gas using silicalite membranes[J]. Sep Purif Technol, 2001,25(1/3):275-286.
13. [13]
  BEMAL M P, CORONAS J, MENÉNDEZ M, SANTAMARIA J. Separation of CO₂/N₂ mixtures using MFI-type zeolite membranes[J]. AIChE J, 2004,50(1):127-135. doi: 10.1002/aic.10012
14. [14]
  MUREDDU M, FERINO I, ROMBI E, CUTRUFELLO M G, DEIANA P, ARDU A, MUSINU A, PICCALUGA G, CANNAS C. ZnO/SBA-15 composites for mid-temperature removal of H₂S:Synthesis, performance and regeneration studies[J]. Fuel, 2012,102:691-700. doi: 10.1016/j.fuel.2012.05.013
15. [15]
  HAFEZ M, MOHAMMAD S. Simultaneous separation of H₂S and CO₂ from CH₄ by a high silica CHA-type zeolite membrane[J]. J Membr Sci, 2014,470:159-165. doi: 10.1016/j.memsci.2014.07.025
16. [16]
  WEICHIH L, YUPEI C, CHINGPING T. Pilot-scale chemical-biological system for efficient H2S removal from biogas[J]. Bioresour Technol, 2013,135:283-291. doi: 10.1016/j.biortech.2012.10.040
17. [17]
  ÁLVAREZ-Cruz R, SÁNCHEZ-FLORES B E, TORRES-GONZÁLEZ J, ANTAÑO-LÓPEZ R, CASTAÑEDA F. Insights in the development of a new method to treat H₂S and CO₂ from sour gas by alkali[J]. Fuel, 2012,100:173-176. doi: 10.1016/j.fuel.2012.05.009
18. [18]
  ŽÁK M, BENDOVÁ H, FRIESS K, BARA J E, IZÁK P. Single-step purification of raw biogas to biomethane quality by hollow fiber membranes without any pretreatment-an innovation in biogas upgrading[J]. Sep Purif Technol, 2018,203(12):36-40.
19. [19]
  WANG S M, WU D, HUANG H L, YANG Q Y, TONG M M, LIU D H, ZHONG C L. Computational exploration of H₂S/CH₄ mixture separation using acid-functionalized UiO-66(Zr) membrane and composites[J]. Chin J Chem Eng, 2015,23:1291-1299. doi: 10.1016/j.cjche.2015.04.017
20. [20]
  YANG W S, ZhANG B Q, LIU X F. Synthesis and characterization of SAPO-5 membranes on porous α-Al₂O₃ substrates[J]. Microporous Mesoporous Mater, 2009,117:391-394. doi: 10.1016/j.micromeso.2008.07.015
21. [21]
  YANG Wen-shen, LANG Lin, WANG Feng-chan, YIN Xiu-li, WU Chuang-zhi. CO₂/CH₄ Separation Performance and CoAPSO-5 Zeolite Membrane Preparation[J]. Trans Chin Soc Agric Mach, 2009,44(9):114-117.
1. [1]
  Pei Li , Yuenan Zheng , Zhankai Liu , An-Hui Lu . Boron-Containing MFI Zeolite: Microstructure Control and Its Performance of Propane Oxidative Dehydrogenation. Acta Physico-Chimica Sinica, 2025, 41(4): 100034-. doi: 10.3866/PKU.WHXB202406012
2. [2]
  Yiping HUANG , Liqin TANG , Yufan JI , Cheng CHEN , Shuangtao LI , Jingjing HUANG , Xuechao GAO , Xuehong GU . Hollow fiber NaA zeolite membrane for deep dehydration of ethanol solvent by vapor permeation. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 225-234. doi: 10.11862/CJIC.20240224
3. [3]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
4. [4]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
5. [5]
  Jiali CHEN , Guoxiang ZHAO , Yayu YAN , Wanting XIA , Qiaohong LI , Jian ZHANG . Machine learning exploring the adsorption of electronic gases on zeolite molecular sieves. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 155-164. doi: 10.11862/CJIC.20240408
6. [6]
  Ke-Ai Zhou , Lian Huang , Xing-Ping Fu , Li-Ling Zhang , Yu-Ling Wang , Qing-Yan Liu . Fluorinated metal-organic framework for methane purification from a ternary CH4/C2H6/C3H8 mixture. Chinese Journal of Structural Chemistry, 2023, 42(11): 100172-100172. doi: 10.1016/j.cjsc.2023.100172
7. [7]
  Yong Shu , Xing Chen , Sai Duan , Rongzhen Liao . How to Determine the Equilibrium Bond Distance of Homonuclear Diatomic Molecules: A Case Study of H₂. University Chemistry, 2024, 39(7): 386-393. doi: 10.3866/PKU.DXHX202310102
8. [8]
  Shanghua Li , Malin Li , Xiwen Chi , Xin Yin , Zhaodi Luo , Jihong Yu . 基于高离子迁移动力学的取向ZnQ分子筛保护层实现高稳定水系锌金属负极的构筑. Acta Physico-Chimica Sinica, 2025, 41(1): 2309003-. doi: 10.3866/PKU.WHXB202309003
9. [9]
  Xiangyu Chen , Aihao Xu , Dong Wei , Fang Huang , Junjie Ma , Huibing He , Jing Xu . Atomic cerium-doped CuO_x catalysts for efficient electrocatalytic CO₂ reduction to CH₄. Chinese Chemical Letters, 2025, 36(1): 110175-. doi: 10.1016/j.cclet.2024.110175
10. [10]
  Xiuzheng Deng , Changhai Liu , Xiaotong Yan , Jingshan Fan , Qian Liang , Zhongyu Li . Carbon dots anchored NiAl-LDH@In₂O₃ hierarchical nanotubes for promoting selective CO₂ photoreduction into CH₄. Chinese Chemical Letters, 2024, 35(6): 108942-. doi: 10.1016/j.cclet.2023.108942
11. [11]
  Hui Li , Yanxing Qi , Jia Chen , Juanjuan Wang , Min Yang , Hongdeng Qiu . Synthesis of amine-pillar[5]arene porous adsorbent for adsorption of CO₂ and selectivity over N₂ and CH₄. Chinese Chemical Letters, 2024, 35(11): 109659-. doi: 10.1016/j.cclet.2024.109659
12. [12]
  Jia-Mei Qin , Xue Li , Wei Lang , Fu-Hao Zhang , Qian-Yong Cao . An AIEgen nano-assembly for simultaneous detection of ATP and H₂S. Chinese Chemical Letters, 2024, 35(6): 108925-. doi: 10.1016/j.cclet.2023.108925
13. [13]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
14. [14]
  Huakang Zong , Xinyue Li , Yanlin Zhang , Faxun Wang , Xingxing Yu , Guotao Duan , Yuanyuan Luo . Pt/Ti₃C₂ electrode material used for H₂S sensor with low detection limit and high stability. Chinese Chemical Letters, 2025, 36(5): 110195-. doi: 10.1016/j.cclet.2024.110195
15. [15]
  Yudi Cheng , Xiao Wang , Jiao Chen , Zihan Zhang , Jiadong Ou , Mengyao She , Fulin Chen , Jianli Li . A near-infrared fluorescent probe for visualizing transformation pathway of Cys/Hcy and H₂S and its applications in living system. Chinese Chemical Letters, 2024, 35(5): 109156-. doi: 10.1016/j.cclet.2023.109156
16. [16]
  Shangqian Zhang , Jiaxuan Li , Xuan Hu , Zelong Chen , Junliang Dong , Chenhao Hu , Shuang Chao , Yinghua Lv , Yuxin Pei , Zhichao Pei . H₂S and NIR light-driven nanomotors induce disulfidptosis for targeted anticancer therapy by enhancing disruption of tumor metabolic symbiosis. Chinese Chemical Letters, 2025, 36(1): 110314-. doi: 10.1016/j.cclet.2024.110314
17. [17]
  Junhua Wang , Xin Lian , Xichuan Cao , Qiao Zhao , Baiyan Li , Xian-He Bu . Dual polarization strategy to enhance CH₄ uptake in covalent organic frameworks for coal-bed methane purification. Chinese Chemical Letters, 2024, 35(8): 109180-. doi: 10.1016/j.cclet.2023.109180
18. [18]
  Lan Ma , Cailu He , Ziqi Liu , Yaohan Yang , Qingxia Ming , Xue Luo , Tianfeng He , Liyun Zhang . Magical Surface Chemistry: Fabrication and Application of Oil-Water Separation Membranes. University Chemistry, 2024, 39(5): 218-227. doi: 10.3866/PKU.DXHX202311046
19. [19]
  Yang YANG , Pengcheng LI , Zhan SHU , Nengrong TU , Zonghua WANG . Plasmon-enhanced upconversion luminescence and application of molecular detection. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 877-884. doi: 10.11862/CJIC.20230440
20. [20]
  Peipei Sun , Jinyuan Zhang , Yanhua Song , Zhao Mo , Zhigang Chen , Hui Xu . 引入内建电场增强光载流子分离以促进H₂的生产. Acta Physico-Chimica Sinica, 2024, 40(11): 2311001-. doi: 10.3866/PKU.WHXB202311001

Get Citation

PDF

XML

Metrics

PDF Downloads(7)
Abstract views(1780)
HTML views(143)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and H2S/CH4 separation performance of MFI type zeolite membrane

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation and H₂S/CH₄ separation performance of MFI type zeolite membrane