Citation: Ma Mingming, Du Ru, Chu Chu. Electrochemical Synthesis of 4, 4'-Oxydianiline Molecular Imprinted Polymer/Poly 4, 4'-Oxydianiline and Its Absorbing Properties[J]. Chemistry, ;2020, 83(1): 80-87. shu

Electrochemical Synthesis of 4, 4'-Oxydianiline Molecular Imprinted Polymer/Poly 4, 4'-Oxydianiline and Its Absorbing Properties

College of Environmental and Chemical Engineering, Xi'an Polytechnic University, Xi'an, 710048

Received Date: 20 June 2019
Revised Date: 13 October 2019
Accepted Date: 1 November 2019

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A novel electromagnetic material 4, 4'-oxydianiline molecular imprinted polymer composite poly 4, 4'-oxydianiline (4, 4'-ODL-MIP/P-4, 4'-ODL) was prepared on the surface of graphene modified pencil electrode (G-PEC) by means of the secondary electrochemical polymerization. The effects of the effective conductive length, the concentration of graphene, pH of buffer, the concentration ratio of 4, 4'-oxydianiline to functional monomer acrylamide, the range of scanning potential, the number of scanning cycles, scanning rate and elution time on the charge of composite materials were investigated. The testing results of the vector network analyzers showed that as-synthesized composite material exhibited a reflection loss of -10.57dB at 12.56MHz, and the effective electromagnetic wave absorption rate reached 90%. However, the reflection loss of a single 4, 4'-ODL-MIP and graphene were both higher than -10 dB, the effective electromagnetic wave absorption rates were only about 68% and 60%, respectively. Therefore, the composite material exhibited good wave absorbing properties.
- 4, 4'-Oxydianiline,
- Molecular imprinted polymer,
- Secondary electrochemical polymerization,
- Charge,
- Electromagnetic wave absorbing
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沈阳化工大学材料科学与工程学院沈阳 110142