Citation: JIAN Yi-ming, LI Xian, ZHU Xian-qing, ASHIDA Ryuichi, WORASUWANNARAK Nakorn, HU Zhen-zhong, LUO Guang-qian, YAO Hong, ZHONG Mei, LIU Jing-mei, MA Feng-yun, MIURA Kouichi. Interaction between low-rank coal and biomass during degradative solvent extraction[J]. Journal of Fuel Chemistry and Technology, ;2019, 47(1): 14-22. shu

Interaction between low-rank coal and biomass during degradative solvent extraction

1.
Key Laboratory of Coal Clean Conversion and Chemical Process Autonomous Region, College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, China
2.
State Key Laboratory of Coal Combustion, College of Energy and Power Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
3.
Department of Chemical Engineering, Kyoto University, Kyoto 615-8510, Japan
4.
The Joint Graduate School of Energy and Environment, Center of Excellence on Energy Technology and Environment, King Mongkut's University of Technology Thonburi, Bangkok 10140, Thailand

Corresponding author: LI Xian, xian_li@hust.edu.cn ZHONG Mei, zhongmei0504@126.com
Received Date: 3 September 2018
Revised Date: 27 November 2018

Fund Project: the National Natural Science Foundation of China 21776109the Key Project of Joint Fund from National Natural Science Foundation of China and the Government of Xinjiang Uygur Autonomous Region U1503293the Double First-Class Research Funding of China-EU Institute for Clean and Renewable Eenergy and the Foundation of State Key Laboratory of Coal Combustion FSKLCCA1602the Double First-Class Research Funding of China-EU Institute for Clean and Renewable Eenergy and the Foundation of State Key Laboratory of Coal Combustion FSKLCCB1805the Youth Science and Technology Innovation Personnel Training Project in Xinjiang Uygur Autonomous Region QN2016BS0152the National Natural Science Foundation of China 21766035The project was supported by the National Natural Science Foundation of China (51661145010, 21776109, U1510119, 21766035), the Youth Science and Technology Innovation Personnel Training Project in Xinjiang Uygur Autonomous Region (QN2016BS0152), the Key Project of Joint Fund from National Natural Science Foundation of China and the Government of Xinjiang Uygur Autonomous Region (U1503293), 111 Project (D18022), the Double First-Class Research Funding of China-EU Institute for Clean and Renewable Eenergy and the Foundation of State Key Laboratory of Coal Combustion (FSKLCCB1805, FSKLCCA1602)the National Natural Science Foundation of China U1510119111 Project D18022the National Natural Science Foundation of China 51661145010

Figures(8)

A degradative solvent extraction at around 350℃ for low-rank coal or biomass wastes upgrading and fractionation was proposed in our previous work. The extraction yield of low-rank coal is relatively lower than that of biomass. In this work the blends of low-rank coal and biomass were treated by this method at 350℃ to investigate the interaction between them. The results showed that the yields and elemental compositions of the extracts obtained from the blends were slight different to the calculated results, which were calculated by assuming that there was no interaction between the coal and biomass. The slight promotion of yield was judged to be caused by the catalytic action of the minerals in the coal for thermal decomposition of biomass. It was worth to note that the elemental composition, molecular weight distribution, chemical structure, thermal decomposition behavior and thermoplastic behavior of the extracts obtained from low-rank coal, biomass and their blend, were rather similar to each other, independent of the properties of the raw feedstocks. Overall, the interaction between low-rank coal and biomass during the extraction was not significant. On the other hand, the proposed degradative solvent extraction method was fit not only by single low-rank coal and biomass but also by their blends to produce the product having similar physicochemical properties. This implied that an industrial system of degradative solvent extraction can use coal, biomass or their blends as feedstock at the same time without modification or adjustment.
- low-rank coal,
- biomass,
- blends,
- degradative solvent extraction,
- upgrading
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