Citation: ZHENG Fang, ZHU Guang-you, CHEN Zhi-qiang, ZHAO Qiu-li, SHI Quan. Molecular composition of vanadyl porphyrins in the gilsonite[J]. Journal of Fuel Chemistry and Technology, ;2020, 48(5): 562-567. shu

Molecular composition of vanadyl porphyrins in the gilsonite

1.
State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing 102249, China
2.
Research Institute of Petroleum Exploration and Development, Petro China, Beijing 100083, China
3.
Guangyuan Shengtong Mining co. LTD, Guangyuan 628000, China

Corresponding author: SHI Quan, geochem@vip.sina.com
Received Date: 24 February 2020
Revised Date: 2 April 2020

Figures(5)

A gilsonite from Qingchuan (Sichuan province, China) was separated into several fractions and characterized by various techniques. The vanadyl porphyrins were determined by inductively coupled plasma optical emission spectrometer, ultraviolet-visible, high-temperature gas chromatography atomic emission detection, and positive-ion electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry. The results show that the gilsonite contains a large amount of metal elements, especially the vanadium content is as high as 3888 μg/g. A large number of vanadyl porphyrins are detected, in which the deoxophylloerythroetio porphyrins are the most abundant, indicating high molecular condensation but low thermal maturity. The huge reserves and high metal content imply important utilization value for this natural source.
- gilsonite,
- vanadium,
- porphyrins,
- high resolution mass spectrometry
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1.
沈阳化工大学材料科学与工程学院沈阳 110142