Citation: CHENG Fu-long, GUO He-qin, CUI Jing-lei, HOU Bo, LI De-bao. Effect of calcination temperature on MgAlO_x mixed oxides for converting formaldehyde and acetaldehyde to propanal[J]. Journal of Fuel Chemistry and Technology, ;2018, 46(7): 841-847. shu

Effect of calcination temperature on MgAlO_x mixed oxides for converting formaldehyde and acetaldehyde to propanal

CHENG Fu-long ^1,2 ,
GUO He-qin ^1,, ,
CUI Jing-lei ³ ,
HOU Bo ¹ ,
LI De-bao ^1,,

1.
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China
3.
Institute of Resources and Environment Engineering, Shanxi University, Taiyuan 030006, China

Corresponding author: GUO He-qin, heqinguo@sxicc.ac.cn LI De-bao, dbli@sxicc.ac.cn
Received Date: 15 January 2018
Revised Date: 11 May 2018

Fund Project: the National Natural Science Foundation of China 21736007The project was supported by the National Natural Science Foundation of China (21736007, 21303241)the National Natural Science Foundation of China 21303241

Figures(6)

A series of MgAlO_x mixed oxides were prepared by calcination of hydrotalcite materials at various temperatures ranging from 400 to 700℃. The physical and chemical properties of the catalysts were characterized by XRD, TG, N₂ adsorption/desorption, NH₃-TPD, and CO₂-TPD techniques. The catalytic activity was evaluated by the condensation of formaldehyde and acetaldehyde. The results show that as the calcination temperatures increase, both the conversion of acetaldehyde and the space time yield of propanal first increase and then decrease, which shows the same trend with the amount of moderate basic sites, and the C-550 catalyst has the maximum of 39.22% and 103.86 g/(kg·h), respectively. Moreover, the yields of by-products including methanol and CO₂ are also significantly related to the moderate and strong basic sites.
- formaldehyde and acetaldehyde,
- propanal,
- MgAlO_x mixed oxides,
- calcination temperature
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Effect of calcination temperature on MgAlOx mixed oxides for converting formaldehyde and acetaldehyde to propanal

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通讯作者: 陈斌, bchen63@163.com

Effect of calcination temperature on MgAlO_x mixed oxides for converting formaldehyde and acetaldehyde to propanal