Citation: BIAN Yu-qing, ZHAO Yuan-sheng, ZHANG Long-li, ZHAO Yu-sheng, YANG Chao-he. Study on the hydrogenation reaction and coking behavior in Golmud residue hydrogenation[J]. Journal of Fuel Chemistry and Technology, ;2019, 47(8): 1016-1024. shu

Study on the hydrogenation reaction and coking behavior in Golmud residue hydrogenation

1.
State Key Laboratory of Heavy Oil, China University of Petroleum(East China), Qingdao 266580, China;
2.
China Petroleum and Petrochemical Research Institute, Beijing 102206, China

Corresponding author: ZHANG Long-li, llzhang@upc.edu.cn
Received Date: 20 May 2019
Revised Date: 25 June 2019

Fund Project: The project was supported by the National Natural Science Foundation of China (21576292)the National Natural Science Foundation of China 21576292

Figures(13)

The ultra-low asphaltene content of Golmud residue (asphaltene content:0.32%) was used as the hydrogenation feedstock. The effect of reaction conditions on the composition properties, colloidal stability parameters (CSP) and coke performance of the hydrogenation reaction samples was investigated. The results show that with the increase in hydrogenation temperature and reaction time, the content of asphaltene and saturated fraction increases, the content of colloid and aromatic fraction as well as the colloid stability parameter decrease, and the coke yield increases continuously. Meanwhile, as the degree of condensation of asphaltenes increases, the aromatic carbon ratio f_A increases continuously, the metals and heteroatoms are continuously removed during hydrogenation, V is easier to remove than Ni, and S is easier to remove than N. On the catalyst surface is a carbon-based substance similar to the graphite with ordered structure formed, leading to the continuous reduction in pore structure parameters of the catalyst. When the reaction temperature and time are 420 ℃ and 5 h, respectively, the pore structure damage of the catalyst is the most serious, and a dominant distribution of micropore appears.
- residue hydrogenation,
- colloidal stability,
- catalyst,
- coke yield
1. [1]
  WANG Hai-yan, QI Zhen-dong, YAN Jing-sen, WEI Min. The effect of ti doping in Ni₂P/SBA-15 catalyst on its catalytic hydrodenitrogenation performance[J]. Acta Pet Sin(Pet Process Sect), 2015,31(6):1281-1288. doi: 10.3969/j.issn.1001-8719.2015.06.005
2. [2]
  LI Z K, WANG G, LIU Y D, GAO J S, XU C M, LIANG Y M, WANG X Q. Study on reaction performance and competitive adsorption effect during coker gas oil catalytic cracking[J]. Fuel Process Technol, 2013,115(11):1-10.
3. [3]
  BU Wei-da. Characteristics and development trend of heavy oil hydrogenation technology[J]. Chem Eng Equip, 2010,3:113-115.
4. [4]
  LIANG Wen-jie. Heavy Oil Chemistry[M]. Shandong:Petroleum University Press, 2000:2-7.
5. [5]
  CERQUEIRA H S, CAEIRO G, COSTA L, RAMÔA R F. Deactivation of FCC catalysts[J]. J Mol Catal A:Chem, 2008,292(1/2):1-13.
6. [6]
  LIU Mei, LIU Tie-bin, YUAN Sheng-hua, ZHAO De-zhi. Transformation of sulfur-containing compounds in hydrotreating of middle east atmospheric residue[J]. Acta Pet Sin(Pet Process Sect), 2016,32(2):319-325. doi: 10.3969/j.issn.1001-8719.2016.02.013
7. [7]
  CAEIRO G, COSTA A F, CERQUEIRA H S, MAGNOUX P, LOPES J M, MATIAS P, RAMÔA R F. Nitrogen poisoning effect on the catalytic cracking of gasoil[J]. Appl Catal A:Gen, 2007,320(3):8-15.
8. [8]
  MAGALLAL. Theoretical Basis of Petrochemical Processing[M]. Translated by XU Yi-fang et al. Beijing: Petroleum Industry Press, 1982: 145-161.
9. [9]
  ZHANG L L, MAO H X, ZHANG G D, YANG G G, LI L, YANG C H. Relationships between electrical conductivity variation and coking characteristics of residue during thermal reaction through online equipment[J]. Energy Fuels, 2016,30(7):5404-5410. doi: 10.1021/acs.energyfuels.6b00453
10. [10]
  ZHANG L L, YANG G H, QUE G H. The conglomerating characteristics of asphaltenes from residue during thermal reaction[J]. Fuel, 2005,84(7):1023-1026.
11. [11]
  JIANG Li-jing. Study on hydrotreating kinetics and combination process of residual oil[D]. Dalian: Dalian University of Technology, 2011.
12. [12]
  LIANG Jing-cheng, MA Shou-tao, ZHOU Yong-li. Analysis of carbon and hydrogen content in evaluation of mixed crude oil[J]. Pet Nat Gas Chem, 2011,40(4):394-395. doi: 10.3969/j.issn.1007-3426.2011.04.017
13. [13]
  WANG Ben, HUANG Ke-Lin, SUN Guo-song, ZHANG Xue-wang, CAO Yong-mei, ZHANG Shou-li. XRD analysis-Application in solid catalyst phase structure research[J]. Public Sci Technol, 2008(12):109-111. doi: 10.3969/j.issn.1008-1151.2008.12.049
14. [14]
  ZHANG H Y, WANG Y, SHAO S S, XIAO R. An experimental and kinetic modeling study including coke formation for catalytic pyrolysis of furfural[J]. Combust Flame, 2016(173):258-265.
15. [15]
  SUN Yu-dong. Influence of raw material composition on hydrogenation performance and catalyst properties of residual oil[D]. Shanghai: East China University of Science and Technology, 2011.
16. [16]
  SHI Q, XU C M, ZHAO S Q, KENG H C, ZHANG Y H, GAO W. Characterization of basic nitrogen species in coker gas oils by positive-ion electrospray ionization fourier transform ion cyclotron resonance mass spectrometry[J]. Energy Fuels, 2010,24(1):563-569.
17. [17]
  ZHANG Hui-cheng, YAN Yong-jie, QI Bang-feng, SUN Wan-fu, ZHANG Hong-yu. Influence of residue hydrotreating on the stability of residue colloid[J]. Pet Nat Gas Chem, 2007,36(3):197-200. doi: 10.3969/j.issn.1007-3426.2007.03.007
18. [18]
  SUN Y D, YANG C H, ZHAO H, SHAN H H, SHEN B X. Influence of asphaltene on the residue hydrotreating reaction[J]. Energy Fuels, 2010,24(9):5008-5011. doi: 10.1021/ef1005385
19. [19]
  LIANG Wen-jie. Heavy Oil Chemistry[M]. Dongying:Petroleum University Press. 1995:64-66.
20. [20]
  ZHAO Hui. Research on hydrogen conversion law of residue oil[D]. Qingdao: China University of Petroleum, 2009.
21. [21]
  YU Shuang-lin. Colloidal properties of residue hydrotreating system[D]. Qingdao: China University of Petroleum, 2010.
22. [22]
  QIAO Jin-shuai, ZHANG Long-li, CHEN Peng-wei, CAO Zhe-zhe, SHAN Hong-hong. Review on the influence of colloid and asphalt quality on the stability of residual oil colloid[J]. Appl Chem Ind, 2017,46(6):1180-1184. doi: 10.3969/j.issn.1671-3206.2017.06.036
23. [23]
  ANCHEYTA J, CENTENO G, TREJO F, SPEIGHT J G. Asphaltene characterization as function of time on-stream during hydroprocessing of Maya crude[J]. Catal Today, 2005,109:162-166. doi: 10.1016/j.cattod.2005.08.004
24. [24]
  QUE Guo-he. Petroleum Composition and Transforming Chemistry[M]. Shandong:Petroleum University Press. 2008:288-380.
25. [25]
  WANG Lei. Research and application of residual oil hydrogenation process[J]. Contemp Chem Ind, 2005,34(3):157-158. doi: 10.3969/j.issn.1671-0460.2005.03.004
26. [26]
  ZHANG H Y, WANG Y, SHAO S S, XIAO R. An experimental and kinetic modeling study including coke formation for catalytic pyrolysis of furfural[J]. Combust Flame, 2016,173:258-265. doi: 10.1016/j.combustflame.2016.08.019
27. [27]
  LIU Yong-jun, ZOU Yu. Carbon deposition analysis of hydro-demetalization catalyst for residue oil[J]. J Huaqiao Univ(Nat Sci Ed), 2014,35(2):180-184.
28. [28]
  ZHANG Hui-cheng, MA Bo, LI Jing-bin, LIU Shu-qin, GENG Jing-yuan, WANG Ji-feng. Analysis of catalyst carbon deposition in residue hydrotreating[J]. Contemp Chem Ind, 2008,37(3):277-282. doi: 10.3969/j.issn.1671-0460.2008.03.016
29. [29]
  LIN Jian-fei, HU Da-wei, YANG Qing-he, NIE Hong. Analysis of carbon deposition on surface of fixed-bed residue hydrotreating catalyst[J]. Pet Process Petrochem, 2016,47(10):1-5. doi: 10.3969/j.issn.1005-2399.2016.10.001
1. [1]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
2. [2]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
3. [3]
  Yongwei ZHANG , Chuang ZHU , Wenbin WU , Yongyong MA , Heng YANG . Efficient hydrogen evolution reaction activity induced by ZnSe@nitrogen doped porous carbon heterojunction. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 650-660. doi: 10.11862/CJIC.20240386
4. [4]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
5. [5]
  Hailian Tang , Siyuan Chen , Qiaoyun Liu , Guoyi Bai , Botao Qiao , Fei Liu . Stabilized Rh/hydroxyapatite Catalyst for Furfuryl Alcohol Hydrogenation: Application of Oxidative Strong Metal-Support Interactions in Reducing Conditions. Acta Physico-Chimica Sinica, 2025, 41(4): 100036-. doi: 10.3866/PKU.WHXB202408004
6. [6]
  Jun LI , Huipeng LI , Hua ZHAO , Qinlong LIU . Preparation and photocatalytic performance of AgNi bimetallic modified polyhedral bismuth vanadate. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 601-612. doi: 10.11862/CJIC.20230401
7. [7]
  Yu Wang , Haiyang Shi , Zihan Chen , Feng Chen , Ping Wang , Xuefei Wang . 具有富电子Pt^δ^-壳层的空心AgPt@Pt核壳催化剂：提升光催化H₂O₂生成选择性与活性. Acta Physico-Chimica Sinica, 2025, 41(7): 100081-. doi: 10.1016/j.actphy.2025.100081
8. [8]
  Shitao Fu , Jianming Zhang , Cancan Cao , Zhihui Wang , Chaoran Qin , Jian Zhang , Hui Xiong . Study on the Stability of Purple Cabbage Pigment. University Chemistry, 2024, 39(4): 367-372. doi: 10.3866/PKU.DXHX202401059
9. [9]
  Fangxuan Liu , Ziyan Liu , Guowei Zhou , Tingting Gao , Wenyu Liu , Bin Sun . Hollow structured photocatalysts. Acta Physico-Chimica Sinica, 2025, 41(7): 100071-. doi: 10.1016/j.actphy.2025.100071
10. [10]
  Yuchen Zhou , Huanmin Liu , Hongxing Li , Xinyu Song , Yonghua Tang , Peng Zhou . Designing thermodynamically stable noble metal single-atom photocatalysts for highly efficient non-oxidative conversion of ethanol into high-purity hydrogen and value-added acetaldehyde. Acta Physico-Chimica Sinica, 2025, 41(6): 100067-. doi: 10.1016/j.actphy.2025.100067
11. [11]
  Xuyang Wang , Jiapei Zhang , Lirui Zhao , Xiaowen Xu , Guizheng Zou , Bin Zhang . Theoretical Study on the Structure and Stability of Copper-Ammonia Coordination Ions. University Chemistry, 2024, 39(3): 384-389. doi: 10.3866/PKU.DXHX202309065
12. [12]
  Xiaoning TANG , Junnan LIU , Xingfu YANG , Jie LEI , Qiuyang LUO , Shu XIA , An XUE . Effect of sodium alginate-sodium carboxymethylcellulose gel layer on the stability of Zn anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1452-1460. doi: 10.11862/CJIC.20240191
13. [13]
  Yingtong Shi , Guotong Xu , Guizeng Liang , Di Lan , Siyuan Zhang , Yanru Wang , Daohao Li , Guanglei Wu . PEG-VN改性PP隔膜用于高稳定性高效率锂硫电池. Acta Physico-Chimica Sinica, 2025, 41(7): 100082-. doi: 10.1016/j.actphy.2025.100082
14. [14]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
15. [15]
  Xuejie Wang , Guoqing Cui , Congkai Wang , Yang Yang , Guiyuan Jiang , Chunming Xu . 碳基催化剂催化有机液体氢载体脱氢研究进展. Acta Physico-Chimica Sinica, 2025, 41(5): 100044-. doi: 10.1016/j.actphy.2024.100044
16. [16]
  Jiaxi Xu , Yuan Ma . Influence of Hyperconjugation on the Stability and Stable Conformation of Ethane, Hydrazine, and Hydrogen Peroxide. University Chemistry, 2024, 39(11): 374-377. doi: 10.3866/PKU.DXHX202402049
17. [17]
  Juntao Yan , Liang Wei . 2D S-Scheme Heterojunction Photocatalyst. Acta Physico-Chimica Sinica, 2024, 40(10): 2312024-. doi: 10.3866/PKU.WHXB202312024
18. [18]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-. doi: 10.3866/PKU.WHXB202405016
19. [19]
  Dan Li , Hui Xin , Xiaofeng Yi . Comprehensive Experimental Design on Ni-based Catalyst for Biofuel Production. University Chemistry, 2024, 39(8): 204-211. doi: 10.3866/PKU.DXHX202312046
20. [20]
  Haodong JIN , Qingqing LIU , Chaoyang SHI , Danyang WEI , Jie YU , Xuhui XU , Mingli XU . NiCu/ZnO heterostructure photothermal electrocatalyst for efficient hydrogen evolution reaction. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1068-1082. doi: 10.11862/CJIC.20250048

Get Citation

PDF

XML

Metrics

PDF Downloads(9)
Abstract views(969)
HTML views(138)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142