手性调控CdS/Co掺杂Ti<sub>3</sub>C<sub>2</sub> MXene肖特基异质结微塑料光重整制取氢气与丙酮酸

引用本文: 李和玉, 李玲娇, 王海余, 刘彬, 陈莲芬, 靳治良. 手性调控CdS/Co掺杂Ti₃C₂ MXene肖特基异质结微塑料光重整制取氢气与丙酮酸[J]. 物理化学学报, 2026, 42(10): 100350. shu

Citation: Heyu Li, Lingjiao Li, Haiyu Wang, Bin Liu, Lianfen Chen, Zhiliang Jin. Chirality regulated CdS/Co-doped Ti₃C₂ MXene Schottky heterojunction for microplastic photoreforming to hydrogen and pyruvic acid[J]. Acta Physico-Chimica Sinica, 2026, 42(10): 100350. shu

手性调控CdS/Co掺杂Ti₃C₂ MXene肖特基异质结微塑料光重整制取氢气与丙酮酸

李和玉 ^1, ,
李玲娇 ^2, ,
王海余 ^{2,
,} ,
刘彬 ^3, ,
陈莲芬 ^4, ,
靳治良 ^{1,
,}

1.
北方民族大学化学与化学工程学院, 国家民委化工技术基础重点实验室, 宁夏太阳能化学转化技术重点实验室, 宁夏银川 750021;
2.
榆林大学化学与化工学院, 陕西榆林 719000;
3.
韶关学院化学与土木工程学院, 广东韶关 512005;
4.
肇庆学院环境与化学工程学院, 广东肇庆 526061

通讯作者: 王海余,E-mail:whyu@yulinu.edu.cn; 靳治良,E-mail:zl-jin@nun.edu.cn

基金项目:
本研究得到了宁夏自然科学基金(2023AAC03285)、陕西省科技厅项目(2025JC-YBQN-139和20250456)、榆林市政府科技计划项目(2025-CXY-168)、榆林市科协人才支持计划(20240611和20250718)以及榆林学院高层次人才启动计划(2024GK17和2025GK27)的资助。

摘要: 手性光催化剂在光催化析氢领域展现出巨大潜力。然而，手性调控的硫化镉(CCdS)仍面临光生电荷分离不足的问题，这限制了其实际应用与进一步发展。本文通过简单物理混合法，构建了由CCdS与Co掺杂Ti₃C₂(CTC)组成的新型肖特基异质结光催化剂(CCdS/CTC)。该光催化剂在5 h内可从聚乳酸(PLA)微塑料中实现21937 μmol g^-1的产氢量，同时将PLA转化为丙酮酸(PA)小分子。X射线光电子能谱(XPS)、原位X射线光电子能谱(原位XPS)及密度泛函理论(DFT)计算证实了CCdS与CTC接触界面的电荷转移。光电化学测试表明，CCdS的手性调控与所构建的异质结协同作用，有效促进了光生电荷的分离与传输。CCdS/CTC界面形成的肖特基异质结进一步提升了CCdS的光生载流子分离效率。手性调控与元素掺杂的协同效应显著抑制了光生电荷复合。本研究提出了一种将废塑料转化为氢燃料的有效策略，为可持续光催化剂的理性设计提供了参考，在环境修复与可再生能源生产领域具有应用潜力。

关键词:

English

Chirality regulated CdS/Co-doped Ti₃C₂ MXene Schottky heterojunction for microplastic photoreforming to hydrogen and pyruvic acid

Heyu Li ^1, ,
Lingjiao Li ^2, ,
Haiyu Wang ^{2,
,} ,
Bin Liu ^3, ,
Lianfen Chen ^4, ,
Zhiliang Jin ^{1,
,}

1.
School of Chemistry and Chemical Engineering, Key Laboratory for Chemical Engineering and Technology, State Ethnic Affairs Commission, Ningxia Key Laboratory of Solar Chemical Conversion Technology, North Minzu University, Yinchuan 750021, Ningxia Hui Autonomous Region, China;
2.
School of Chemistry and Chemical Engineering, Yulin University, Yulin 719000, Shaanxi Province, China;
3.
School of Chemistry and Civil Engineering, Shaoguan University, Shaoguan 512005, Guangdong Province, China;
4.
School of Environmental and Chemical Engineering, Zhaoqing University, Zhaoqing 526061, Guangdong Province, China

Corresponding author: Haiyu Wang, ; Zhiliang Jin,

Received Date: 10 May 2026
Accepted Date: 16 June 2026
Revised Date: 09 June 2026

Abstract: Chiral photocatalysts show significant promise for photocatalytic hydrogen evolution. However, chirality-regulated cadmium sulfide (CCdS) continues to suffer from insufficient photogenerated charge separation, which restricts its practical application and further advancement. Herein, we construct a novel Schottky heterojunction photocatalyst (CCdS/CTC) composed of CCdS and Co-doped Ti₃C₂ (CTC) via a simple physical mixing method. Notably, the photocatalyst achieves a hydrogen yield of 21937 μmol g^-1 from polylactic acid (PLA) microplastics within 5 h, accompanied by simultaneous conversion of PLA into pyruvic acid (PA) small molecules. X-ray photoelectron spectroscopy (XPS) and density functional theory (DFT) calculations demonstrate the interfacial charge transfer between CCdS and CTC upon contact, and in situ XPS confirms the charge transfer under illumination. Photoelectrochemical measurements demonstrate that the chirality regulation of CCdS works synergistically with the constructed heterojunction to effectively promote photogenerated charge separation and transport. The Schottky heterojunction formed at the CCdS/CTC interface further enhances the photogenerated carrier separation efficiency of CCdS. The synergy between chirality regulation and elemental doping markedly suppresses photogenerated charge recombination and optimizes surface reaction kinetics. This work presents a promising approach for converting plastic waste into H₂ fuel, offering critical insights into the rational design of sustainable photocatalysts for environmental remediation and renewable energy production.

Key words:

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

手性调控CdS/Co掺杂Ti₃C₂ MXene肖特基异质结微塑料光重整制取氢气与丙酮酸

通讯作者: 王海余,E-mail:whyu@yulinu.edu.cn; 靳治良,E-mail:zl-jin@nun.edu.cn

English

Chirality regulated CdS/Co-doped Ti₃C₂ MXene Schottky heterojunction for microplastic photoreforming to hydrogen and pyruvic acid

Corresponding author: Haiyu Wang, ; Zhiliang Jin,

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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中国化学会秘书处

手性调控CdS/Co掺杂Ti3C2 MXene肖特基异质结微塑料光重整制取氢气与丙酮酸

通讯作者: 王海余,E-mail:whyu@yulinu.edu.cn; 靳治良,E-mail:zl-jin@nun.edu.cn

English

Chirality regulated CdS/Co-doped Ti3C2 MXene Schottky heterojunction for microplastic photoreforming to hydrogen and pyruvic acid

Corresponding author: Haiyu Wang, ; Zhiliang Jin,

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

手性调控CdS/Co掺杂Ti₃C₂ MXene肖特基异质结微塑料光重整制取氢气与丙酮酸

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