Citation: CUI Wei-yi, WANG Xi-yue, TAN Nai-di. Effect of calcination temperature on catalytic performance of Pt-FeO_x/γ-Al₂O₃ catalysts for HCHO oxidation[J]. Journal of Fuel Chemistry and Technology, ;2019, 47(8): 964-972. shu

Effect of calcination temperature on catalytic performance of Pt-FeO_x/γ-Al₂O₃ catalysts for HCHO oxidation

CUI Wei-yi ^1,2 ,
WANG Xi-yue ² ,
TAN Nai-di ^2,,

1.
The Key Laboratory of Chemical Cleaner Production Technology of Jilin Province, Jilin Institute of Chemical Technology, Jilin 132022, China;
2.
College of Chemical and Pharmaceutical Engineering, Jilin Institute of Chemical Technology, Jilin 132022, China

Corresponding author: TAN Nai-di, tannd0119@163.com
Received Date: 28 March 2019
Revised Date: 20 May 2019

Fund Project: The project was supported by the National Science Foundation of China (51805207), 13th Five-Year Science and Technology Research and Planning Project of Education Department of Jilin province(JJKA20180559KJ) and Science and Technology Innovation Development Plan Project of Jilin(201750211)the National Science Foundation of China 5180520713th Five-Year Science and Technology Research and Planning Project of Education Department of Jilin province JJKA20180559KJScience and Technology Innovation Development Plan Project of Jilin 201750211

Figures(10)

A series of Pt-FeO_x/γ-Al₂O₃ catalysts were prepared by colloid-deposition method and characterized by XRD, TEM, BET, XPS, H₂-TPR and FT-IR to investigate the effects of calcination temperature on the surface structure of Pt-FeO_x/γ-Al₂O₃ catalyst and its catalytic performance in catalytic HCHO oxidation. The characterization results showed that the applied calcination temperature greatly influenced the redox properties and chemical states of the Pt species, as well as the amount of surface hydroxyl groups. All resultant Pt-FeO_x/γ-Al₂O₃ catalysts demonstrated activity in HCHO oxidation. The sample with calcination at 200 ℃ exhibited the best performance, which afforded 100% conversion of HCHO into CO₂ and H₂O at room temperature. The catalysts with lower calcination temperature should be beneficial to have a better valence distribution of Pt species and produce more accessible interface active sites like Pt-O-Fe species, thus endowing Pt-FeO_x/γ-Al₂O₃ catalyst with relatively high activity for the oxidation of formaldehyde under mild conditions.
- formaldehyde,
- catalytic oxidation,
- reactivity,
- calcination temperature,
- Pt nanoparticles
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Effect of calcination temperature on catalytic performance of Pt-FeOx/γ-Al2O3 catalysts for HCHO oxidation

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通讯作者: 陈斌, bchen63@163.com

Effect of calcination temperature on catalytic performance of Pt-FeO_x/γ-Al₂O₃ catalysts for HCHO oxidation