Citation: Heng Yi ZHANG, Yu LIU. Molecular Design of Crown Ethers.191.Synthesis of Novel Disulfide-and Diselenide-Bridged Bis (benzo-12-crown-4)s and their Ag⁺ Selective Electrode Properties[J]. Chinese Chemical Letters, ;2000, 12(2): 115-118. shu

Molecular Design of Crown Ethers.191.Synthesis of Novel Disulfide-and Diselenide-Bridged Bis (benzo-12-crown-4)s and their Ag⁺ Selective Electrode Properties

Heng Yi ZHANG ,
Yu LIU

Department of Chemistry Nankai University Tianjin 300071

Received Date: 3 August 1999

Two novel heteroatom–bridged bis (benzo-12-crown-4 ether)s, i.e.bis [2-nitro-4,5-(1,4,7,10-tetraoxadecamethylene)phenyl] disulfide 1 and diselenide 2, have been synthesized.X-ray crystallographic structure was obtained for 1.Ion selective electrodes (ISE) for Ag⁺, containing 1 and 2 in PVC membrane as neutral carriers, were prepared, and their selectivity coefficients for Ag⁺ (k_ag.al^pot) were determined against other heavy metal ions, alkali and alkaline-earth metal ions, and ammonium ion.These ISEs showed excellent Ag⁺ selectivities, logk_ag.al^pot≤-3.8, against most of the interfering cations examined, except for Hg⁺.
- Heteroatom–bridged bis (benzo-12-crown-4 ether)s, ion selective electrodes, selectivity coefficients.
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