Citation: Pei Feng XING, Peng Ji ZHAO, Rui Liang HUANG, Ze Ning HUANG, Xue An CHEN, Hong LIANG, Zhi Guang QIAN. Synthesis and Crystal Structure of [Pd(NH₃)₄]Cl₂·2[Pd(NH₃)₃Cl]Cl[J]. Chinese Chemical Letters, ;1997, 8(3): 259-262. shu

Synthesis and Crystal Structure of [Pd(NH₃)₄]Cl₂·2[Pd(NH₃)₃Cl]Cl

a Southwest Institute of Nuclear Physics and Chemistry, P. O. Box 527-75 Chengdu 610003;
b Institute of Chemistry, Academia Sinica, Beijing 100080

Received Date: 12 November 1996

A new type of ammine palladium(Ⅱ) chloride was prepared by evaporating the solution of [Pd(NH₃)]₄Cl₂ at room temperature.Its crystal structure was refined from single-crystal X-ray data:P4₂/nmc,a=10.5390(10)Å,c=16.905(3)Å,Z=2,and R=0.0357 for 731 structure factors and 52 variable parameters.The framework of the title compound is composed of three sorts of structural units: [Pd(NH₃)₄]²⁺, [Pd(NH₃)₃Cl]⁺,and Cl^-,of which the first kind of least squares plane exhibits distortion in some degree.
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