Citation: LI Shu-na, SONG Pei, ZHANG Jin-li, HE Xiao-xia, XIE Yi-xin, ZHANG Ya-gang, WANG Rui-yi, LI Zhi-kai, ZHU Hua-qing. Morphological effect of CeO₂-MnO_x catalyst on their catalytic performance in lean methane combustion[J]. Journal of Fuel Chemistry and Technology, ;2018, 46(5): 615-624. shu

Morphological effect of CeO₂-MnO_x catalyst on their catalytic performance in lean methane combustion

LI Shu-na ^1,, ,
SONG Pei ¹ ,
ZHANG Jin-li ¹ ,
HE Xiao-xia ¹ ,
XIE Yi-xin ¹ ,
ZHANG Ya-gang ² ,
WANG Rui-yi ³ ,
LI Zhi-kai ^3,, ,
ZHU Hua-qing ^3,,

1.
School of Chemical Engineering, Xi'an University, Xi'an Engineering Research Center of Environmental Detection and Food Safety, Xi'an 710065, China
2.
College of Chemistry and Chemical Engineering, Xi'an University of Science and Technology, Xi'an 710054, China
3.
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China

Corresponding author: LI Shu-na, lishuna165@126.com LI Zhi-kai, lizhikai@sxicc.ac.cn ZHU Hua-qing, zhhq@sxicc.ac.cn
Received Date: 8 February 2018
Revised Date: 8 April 2018

Fund Project: Natural Science Foundation of Education Department of Shaanxi Province 15JK1491the Natural Science Foundation of Shaanxi Province of China 2016JQ2030the Special Natural Science Foundation of Science and Technology Bureau of Xian City CXY1531WL03the Special Natural Science Foundation of Science and Technology Bureau of Xian City 2017CGWL24the Natural Science Foundation of Shaanxi Province of China 2016JQ2017the National Natural Science Foundation of China 51704240The project was supported by the National Natural Science Foundation of China (51704240, 21703276, 51602253), the Natural Science Foundation of Shaanxi Province of China (2016JQ2030, 2016JQ2017), Natural Science Foundation of Education Department of Shaanxi Province (15JK1491), the Special Natural Science Foundation of Science and Technology Bureau of Xian City (2017CGWL24, CXY1531WL03) and College Students' Innovation and Entrepreneurship Program project of Shaanxi Province in 2017the National Natural Science Foundation of China 21703276the National Natural Science Foundation of China 51602253

Figures(10)

Ship-like, oblate spheroid and nano sheet CeO₂-MnO_x mixed oxides were prepared by hydrothermal method and characterized by N₂ sorption, XRD, SEM, TEM, H₂-TPR, Raman spectra and XPS. The relationship between the structure of CeO₂-MnO_x and their catalytic performance in lean methane combustion were then investigated. The results reveal that the catalytic performance of the mixed CeO₂-MnO_x oxide was greatly depended on its morphology. Among all of the samples, the mixed oblate spheroid CeO₂-MnO_x oxides with most oxygen vacancies, Ce³⁺ content and surface active oxygen exhibited the highest activity in lean methane combustion, with a complete CH₄ conversion at 540℃. Following it, the mixed ship-like CeO₂-MnO_x oxides catalyst had 94.05% of the CH₄ conversion at 540℃. On the contrast, the mixed nano sheet CeO₂-MnO_x oxides catalyst presented the lowest catalytic activity with only 89.68% CH₄ conversion at the same reaction temprature owing to its lower oxygen vacancies and surface active oxygen.
- ceria,
- manganese oxide,
- lean methane,
- catalytic combustion,
- morphology
1. [1]
  SU S, BEATH A, GUO H, MALLETT C. An assessment of mine methane mitigation and utilisation technologies[J]. Prog Energy Combust Sci, 2005,31(2):123-170. doi: 10.1016/j.pecs.2004.11.001
2. [2]
  DEBBAGH M N, LECEA C S M D, PÉREZ-RAMÍREZ J. Catalytic reduction of N₂O over steam-activated FeZSM-5 zeolite:Comparison of CH₄, CO, and their mixtures as reductants with or without excess O₂[J]. Appl Catal B:Environ, 2007,70(1/4):334-341.
3. [3]
  LUO J J, XU H Y, LIU Y F, CHU W, JIANG C F, ZHAO X S. A facile approach for the preparation of biomorphic CuO-ZrO₂ catalyst for catalytic combustion of methane[J]. Appl Catal A:Gen, 2012,423/424:121-129. doi: 10.1016/j.apcata.2012.02.025
4. [4]
  ZHANG Jia-jin, LI Jian-wei, ZHU Ji-qin, WANG Yue, CHEN Biao-hua. Effect of promoter on the performance of Cu-Mn complex oxide monolithic catalysts for lean methane catalytic combustion[J]. Chin J Catal, 2011,32(8):1380-1386.
5. [5]
  SI R, FLYTZANI-STEPHANOPOULOS M. Shape and crystal-plane effects of nanoscale ceria on the activity of Au-CeO₂ catalysts for the water-gas shift reaction[J]. Angew Chem Int Ed, 2008,47(15):2884-2887. doi: 10.1002/(ISSN)1521-3773
6. [6]
  TANG X F, CHEN J L, LI Y G, LI Y, XU Y D, SHEN W J. Complete oxidation of formaldehyde over Ag/MnO_x-CeO₂ catalysts[J]. Chem Eng J, 2006,118(1/2):119-125.
7. [7]
  LI H J, QI G, TA N, ZHANG X J, LI W, SHEN W J. Morphological impact of manganese-cerium oxides on ethanol oxidation[J]. Catal Sci Technol, 2011,1(9):1677-1682. doi: 10.1039/c1cy00308a
8. [8]
  WANG X Y, KANG Q, LI D. Low-temperature catalytic combustion of chlorobenzene over MnO_x-CeO₂ mixed oxide catalysts[J]. Catal Commun, 2008,9(13):2158-2162. doi: 10.1016/j.catcom.2008.04.021
9. [9]
  LI J, ZHU P F, ZHOU R X. Effect of the preparation method on the performance of CuO-MnO_x-CeO₂ catalysts for selective oxidation of CO in H₂-rich streams[J]. J Power Sources, 2011,196(22):9590-9598. doi: 10.1016/j.jpowsour.2011.07.052
10. [10]
  ZHANG Y G, QIN Z F, WANG G F, ZHU H Q, DONG M, LI S N, WU Z W, LI Z K, WU Z H, ZHANG J, HU T D, FAN W B, WANG J G. Catalytic performance of MnO_x-NiO composite oxide in lean methane combustion at low temperature[J]. Appl Catal B:Environ, 2013,129(2):172-181.
11. [11]
  LI S N, ZHU H Q, QIN Z F, WANG G F, ZHANG Y G, WU Z W, LI Z K, CHEN G, DONG W W, WU Z H, ZHENG L R, ZHANG J, HU T D, WANG J G. Morphologic effects of nano CeO₂-TiO₂ on the performance of Au/CeO₂-TiO₂ catalysts in low-temperature CO oxidation[J]. Appl Catal B:Environ, 2014,144(2):498-506.
12. [12]
  MA C J, WEN Y Y, YUE Q Q, LI A Q, ZHANG N W, GAI H J, ZHENG J B, CHEN B H. Oxygen-vacancy-promoted catalytic wet air oxidation of phenol from MnO_x-CeO₂[J]. RSC Adv, 2017,7(43):27079-27088. doi: 10.1039/C7RA04037G
13. [13]
  ZHANG P F, LU H F, ZHOU Y, ZHANG L, WU Z L, YANG S Z, SHI H L, ZHU Q L, CHEN Y F, DAI S. Mesoporous MnCeO_x solid solutions for low temperature and selective oxidation of hydrocarbons[J]. Nat Commun, 2015,6:8448-8458. doi: 10.1038/ncomms9448
14. [14]
  TANG X F, LI Y G, HUANG X M, XU Y D, ZHU H Q, WANG J G, SHEN W J. MnO_x-CeO₂ mixed oxide catalysts for complete oxidation of formaldehyde:Effect of preparation method and calcination temperature[J]. Appl Catal B:Environ, 2006,62(3/4):265-273.
15. [15]
  CEN W L, LIU Y, WU Z B, WANG H Q, WENG X L. A theoretic insight into the catalytic activity promotion of CeO₂ surfaces by Mn doping[J]. Phys Chem Chem Phys, 2012,14(16):5769-5777. doi: 10.1039/c2cp00061j
16. [16]
  FRANCISCO M S P, MASTELARO V R, NASCENTE P A P, FLORENTINO A O. Activity and characterization by XPS, HR-TEM, Raman spectroscopy, and BET surface area of CuO/CeO₂-TiO₂ catalysts[J]. J Phys Chem B, 2001,105(43):10515-10522. doi: 10.1021/jp0109675
17. [17]
  LI Shu-na, SHI Qi, LI Xiao-jun, FANG Zhen-hua, SUN Ping, ZHOU Yue-hua, ZHANG Xing-mei, YANG Xiao-hui. Low temperature CO oxidation over the ceria oxide catalysts doped with Fe, Ni and Cu[J]. J Fuel Chem Technol, 2017,45(6):707-713.
18. [18]
  LI Lan, HU Geng-shen, LU Ji-qing, LUO Meng-fei. Review of oxygen vacancies in CeO₂-doped solid solutions as characterized by Raman spectroscopy[J]. Acta Phys-Chim Sin, 2012,28(5):1012-1020.
19. [19]
  HERNÁNDEZ W Y, CENTENO M A, ROMERO-SARRIA F, ODRIOZOLA J A. Synthesis and characterization of Ce_1-xEu_xO_2-x/2 mixed oxides and their catalytic activities for CO oxidation[J]. J Phys Chem C, 2009,113(14):5629-5635. doi: 10.1021/jp8092989
20. [20]
  HUA G M, ZHANG L D, FEI G T, FANG M. Enhanced catalytic activity induced by defects in mesoporous ceria nanotubes[J]. J Mater Chem, 2012,22(14):6851-6855. doi: 10.1039/c2jm13610d
21. [21]
  BÊCHE E, CHARVIN P, PERARNAU D, ABANADES S, FLAMANT G. Ce 3d XPS investigation of cerium oxides and mixed cerium oxide (Ce_xTi_yO_z)[J]. Surf Interface Anal, 2008,40(3/4):264-267.
22. [22]
  LI S N, ZHANG Y G, LI X J, YANG X H, LI Z K, WANG R Y, ZHU H Q. Preferential oxidation of CO in H₂-rich stream over Au/CeO₂-NiO catalysts:Effect of the preparation method[J]. Catal Lett, 2018,148(1):328-340. doi: 10.1007/s10562-017-2231-1
23. [23]
  SKORODUMOVA N V, SIMAK S I, LUNDQVIST B I, ABRIKOSOV I A, JOHANSSON B. Quantum origin of the oxygen storage capability of ceria[J]. Phys Rev Lett, 2002,89(16):166601-1166601-4. doi: 10.1103/PhysRevLett.89.166601
24. [24]
  YUAN Shan-liang, LAN Hai, BO Qi-fei, ZHANG Biao, XIAO Xi, JIANG Yi. Effect of TiO₂ doping on methane catalytic combustion deoxidation of CuMnCe/Al₂O₃ catalyst[J]. J Fuel Chem Technol, 2017,45(2):243-248.
25. [25]
  HAMOUDI S, LARACHI F, ADNOT A, SAYARI A. Characterization of spent MnO₂/CeO₂ wet oxidation catalyst by TPO-MS, XPS, and S-SIMS[J]. J Catal, 1999,185(2):333-334. doi: 10.1006/jcat.1999.2519
26. [26]
  DELIMARIS D, IOANNIDES T. VOC oxidation over MnO_x-CeO₂ catalysts prepared by a combustion method[J]. Appl Catal B:Environ, 2008,84(1/2):303-312.
27. [27]
  ZHAO P, WANG C N, HE F, LIU S T. Effect of ceria morphology on the activity of MnO_x/CeO₂ catalysts for the catalytic combustion of chlorobenzene[J]. RSC Adv, 2014,4(86):45665-45672. doi: 10.1039/C4RA07843H
28. [28]
  ŚWIATOWSKA J, LAIR V, PEREIRA-NABAIS C, COTE G, MARCUS P, CHAGNES A. XPS, XRD and SEM characterization of a thin ceria layer deposited onto graphite electrode for application in lithium-ion batteries[J]. Appl Surf Sci, 2011,257(21):9110-9119. doi: 10.1016/j.apsusc.2011.05.108
29. [29]
  TROVARELLI A. Catalytic properties of ceria and CeO-containing materials[J]. Catal Rev, 1996,38(4):439-520. doi: 10.1080/01614949608006464
30. [30]
  LU H, KONG X, HUANG H, ZHOU Y, CHEN Y. Cu-Mn-Ce ternary mixed-oxide catalysts for catalytic combustion of toluene[J]. J Environ Sci, 2015,32(6):102-107.
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沈阳化工大学材料科学与工程学院沈阳 110142

Morphological effect of CeO2-MnOx catalyst on their catalytic performance in lean methane combustion

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通讯作者: 陈斌, bchen63@163.com

Morphological effect of CeO₂-MnO_x catalyst on their catalytic performance in lean methane combustion