Citation: Jing Wei LI, Wei SUN, Li Wen XU, Chun Gu XIA, Hong Wang WANG. Room Temperature Ionic Liquid: a Powerful Additive of Mn(Salen) Catalyzed Oxidation of sec-Alcohols[J]. Chinese Chemical Letters, ;2004, 15(12): 1437-1440. shu

Room Temperature Ionic Liquid: a Powerful Additive of Mn(Salen) Catalyzed Oxidation of sec-Alcohols

State Key Laboratory for Oxo Synthesis & Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sicences, Lanzhou 730000

Received Date: 10 November 2003

Fund Project: We thank the National Natural Science Foundation of China (No. 29933050 and No. 20373082). References and Notes

A simple, mild, efficient Mn(salen)-catalyzed oxidation system of secondary alcohols, in which the ionic liquid[bmim]PF₆ acts as a powerfiil additive, has been described. The reaction proceeded with higher efficiency. The catalyst was more easier to recycle in ionic liquid[bmim]PF₆ with a well-proportioned CH₂Cl₂ than in the single CH₂Cl₂ or ionic liquid.
- Salen Mn,
- ionic liquid,
- sec-alcohols,
- oxidation
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