Citation: Wang Hongmei, Bai Jin, Yang Lina, Li Jian. Research Progress in Catalytic Hydrodesulfurization Mechanism of Transition Metal Phosphides[J]. Chemistry, ;2017, 80(4): 349-355. shu

Research Progress in Catalytic Hydrodesulfurization Mechanism of Transition Metal Phosphides

College of Chemistry, Chemical Engineering, and Environmental Engineering, Liaoning Shihua University, Fushun 113001

Corresponding author: Bai Jin, baijin_fy@163.com
Received Date: 8 August 2016
Accepted Date: 15 November 2016

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In this paper the mechanism of the hydrodesulfurization (HDS) reaction of sulfur-containing compounds over bulk transition metal phosphide catalysts, supported transition metal phosphide catalysts, and modified transition metal phosphide catalysts were reviewed. The structure-activity relationships of catalysts, the influence of different types of catalysts on the reaction paths of sulfur-containing compounds over catalysts were also discussed in detail. The calculation of rate constant of different HDS steps over phosphide catalyst led to a better understanding of HDS reaction steps. These results can also help us to understand the reaction kinetics and reaction network of sulfur-containing compounds over phosphide catalysts, which offers an important academic value and general guiding significance for the development and application of new-style deep HDS catalyst.
- Hydrodesulfurization,
- Transition metal phosphides,
- Reaction network,
- Dibenzothiophene,
- Mechanism
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