Citation: REN Shi-biao, ZHANG Sheng, ZHAO Rong, WANG Zhi-cai, LEI Zhi-ping, PAN Chun-xiu, KANG Shi-gang, SHUI Heng-fu. Nanosheets of Ni/Clay as high efficient catalysts for hydrogenation of aromatics[J]. Journal of Fuel Chemistry and Technology, ;2018, 46(2): 171-178. shu

Nanosheets of Ni/Clay as high efficient catalysts for hydrogenation of aromatics

Anhui Key Laboratory of Coal Clean Conversion & Utilization, School of Chemistry and Chemical Engineering, Anhui University of Technology, Ma'anshan 243002, China

Corresponding author: REN Shi-biao, rensb@ahut.edu.cn SHUI Heng-fu, shhf@ahut.edu.cn
Received Date: 7 December 2017
Revised Date: 3 January 2018

Fund Project: the Natural Scientific Foundation of China 21476004the Natural Scientific Foundation of China 21776001The project was supported by the Project of Coal Joint Fund from Natural Science Foundation of China and Shenhua Group Corporation Limited (U1361125, U1261208), the Natural Scientific Foundation of China (21776001, 21476002, 21476003, 21476004), the Key Science and Technology Program of Anhui Province, China (1501041131) and the Provincial Innovative Group for Processing & Clean Utilization of Coal Resourcethe Project of Coal Joint Fund from Natural Science Foundation of China and Shenhua Group Corporation Limited U1261208the Key Science and Technology Program of Anhui Province, China 1501041131the Natural Scientific Foundation of China 21476003the Natural Scientific Foundation of China 21476002the Project of Coal Joint Fund from Natural Science Foundation of China and Shenhua Group Corporation Limited U1361125

Figures(6)

Using montmorillonite (MMT), a natural layered clay, as the layered precursor, nanosheets of Ni/MMT are obtained via a facile method, in which the nickel components are introduced on to the surface of the exfoliated MMT nanosheets dispersed in water via deposition-precipitation with nickel nitrate and urea. Due to their unique properties originated from the two-dimensional (2D) structure, which favors mass transfer and diffusion of the aromatics and their hydrogenation products over the catalyst during reaction, the obtained nanosheets of Ni/Clay show higher efficient for hydrogenation of aromatics than Ni/SBA-15 and Ni/γ-Al₂O₃ catalysts. And the highest TOF for hydrogenation of tetralin over the nanosheets of Ni/Clay is obtained as nickel loading being high to 18.5%.
- nanaosheets,
- Ni/Clay,
- montmorillonite,
- hydrogenation,
- aromatics
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