Citation: Wang Liping, Zhao Licheng, Zhang Linyan. Synthesis of Oligomeric Polycarbonate Diol Catalyized by Mesoporous ZnO Microspheres derived from IRMOF-1[J]. Chemistry, ;2018, 81(8): 705-712. shu

Synthesis of Oligomeric Polycarbonate Diol Catalyized by Mesoporous ZnO Microspheres derived from IRMOF-1

College of Chemistry and environmental science, Qujing Normal University, Qujing 655011, China

Received Date: 23 March 2018
Accepted Date: 14 May 2018

Figures(11)

IRMOF-1 is one of the most classic IRMOF series MOFs materials. Three ZnO catalysts were prepared by heat treatment of IRMOF-1 directly in air at different temperatures, and the crystal structure, morphology, pore structure and surface alkalinity of the samples were characterized by XRD, SEM, BET measurements and CO₂-TPD. The results showed that as-prepared ZnO are a typical mesoporous material with spherical structure, their BET surfcae area and pore size are 49.7~62.2 m²/g and 2.18~2.92 nm, respectively. The catalytic activities of mesoporous ZnO microspheres for the synthesis polycarbnate diol via diphenyl carbonate and neopentyl glycol (NPG) were investigated. The results exhibited that the ZnO microspheres obtained at 500℃ exhibit good catalytic activity in the transesterification of DPC and NPG.
- Metal-organic frameworks,
- ZnO,
- Catalysis,
- Polycarbonate diol,
- Transesterification
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沈阳化工大学材料科学与工程学院沈阳 110142