Citation: WU Da-kai, WANG Xu, GAO Xin-hua, MA Qing-xiang, ZHANG Jian-li, FAN Su-bing, ZHAO Tian-sheng. Preparation of layered K-Fe-Zn-Ti catalyst and its performance in the hydrogenation of carbon dioxide to light olefins[J]. Journal of Fuel Chemistry and Technology, ;2019, 47(8): 949-956. shu

Preparation of layered K-Fe-Zn-Ti catalyst and its performance in the hydrogenation of carbon dioxide to light olefins

State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering, Ningxia University, Yinchuan 750021

Corresponding author: GAO Xin-hua, gxh@nxu.edu.cn ZHANG Jian-li, zhangjl@nxu.edu.cn
Received Date: 22 March 2019
Revised Date: 9 May 2019

Fund Project: the Key R & D Project of Ningxia 2018BEE03010the Natural Science Foundation of Ningxia 2018AAC02002The project was supported by the National Natural Science Foundation of China (21666030), the Natural Science Foundation of Ningxia (2018AAC02002) and the Key R & D Project of Ningxia (2018BEE03010)the National Natural Science Foundation of China 21666030

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A series of layered K-Fe-Zn-Ti catalysts with different Zn/Fe molar ratios were prepared by high-temperature solid state reaction and characterized by SEM, TEM, XRD, H₂-TPR, CO₂-TPD, XPS, N₂ sorption and TG measurements; the performance of K-Fe-Zn-Ti catalysts in the hydrogenation of CO₂ to light olefins was investigated. The results indicate that the K-Fe-Zn-Ti catalysts have the typical layered structure with K_2.3Fe_2.3Ti_5.7O₁₆ as the main phase. ZnFe₂O₄ appears on the Zn promoted K-Fe-Zn-Ti catalysts, which may reduce the crystallinity, enhance the surface basicity, and promote the adsorption of CO₂. The K-Fe-Zn-Ti catalysts exhibit high selectivity to olefins in CO₂ hydrogenation; the ratio of olefins to paraffins in the products (O/P) is higher than 6.5. The addition of Zn can enhance the formation of C₅⁺ hydrocarbons and especially C₄⁺ linear alpha-olefins (LAOs); the content of LAOs in C₄⁺ hydrocarbons over Zn promoted K-Fe-Zn-Ti reaches 75.2%, in comparison with the value of 54.6% over the Zn-free K-Fe-Ti catalyst. In particular, the 0.8K-1.8Fe-0.6Zn-1.3Ti catalyst displays the highest O/P value (7.8), although the effect of Zn content in the Zn-promoted K-Fe-Zn-Ti catalysts on the yield of heavy hydrocarbons and selectivity to alpha-olefins is less significant. Moreover, the K-Fe-Zn-Ti catalysts display high stability in CO₂ hydrogenation and the LMO structure remains almost intact after a long term reaction test of 100 h.
- layered K-Fe-Zn-Ti catalyst,
- CO₂ hydrogenation,
- light olefins,
- linear α-olefins
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