Citation: Sheng Gao LIU, Pei Ji Wu, Dao Ben ZHU. PREPARATION, ELECTRICAL PROPERTIES AND CRYSTAL STRUCTURE OF TWO NEW CHARGE-TRANSFER SALTS (BEDT-TTF) ₃Cu₂Brx AND (TTM-TTF) (Cu₂Bry) (y~4.72)[J]. Chinese Chemical Letters, ;1994, 5(9): 803-806. shu

PREPARATION, ELECTRICAL PROPERTIES AND CRYSTAL STRUCTURE OF TWO NEW CHARGE-TRANSFER SALTS (BEDT-TTF) ₃Cu₂Brx AND (TTM-TTF) (Cu₂Bry) (y~4.72)

Institute of Chemistry, Academia Sinica, Beijing 100080

Received Date: 8 June 1994

Two new organic conductor-semiconductor with Cu-containing binuclear polyhalide complex anion (BEDT-TTF)₃Cu₂Brx(A) and (TTM-TTF) (Cu₃Bry) (B) are prepared and the crystal structure of B is determined,The conductivity of the crystal A and B at room temperature along the crystal growth direction is about 10 and 7■10^-4 S.cm^-1,respectively.
1. [1]
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13. [13]
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14. [14]
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15. [15]
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16. [16]
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17. [17]
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18. [18]
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19. [19]
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20. [20]
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