Citation: ZHANG Jin, LI Xiao-hua, DONG Liang-xiu, WANG Jia-jun, LIU Sha, CAI Yi-xi, SHAO Shan-shan, ZHANG Xiao-lei, HU Chao. Online upgrading of bio-oil with alkali-treated HZSM-5 zeolites[J]. Journal of Fuel Chemistry and Technology, ;2017, 45(7): 828-836. shu

Online upgrading of bio-oil with alkali-treated HZSM-5 zeolites

Department of Automotive and Traffic Engineering, Jiangsu University, Zhenjiang 212013, China

Corresponding author: LI Xiao-hua, lixiaohua@ujs.edu.cn
Received Date: 23 February 2017
Revised Date: 27 April 2017

Fund Project: the National Natural Science Foundation of China 51276085the Priority Academic Program Development of Jiangsu Higher Education Institutions PDPA

Figures(10)

HZSM-5 zeolite was treated by sodium hydroxide solution, and then characterized by XRD, SEM, BET and Py-FTIR, respectively. Physical and chemical properties and composition analysis was applied to the organic phase of bio-oils. Thermogravimetric analysis was performed on three deactivated catalysts after using for 120 min and the peak area of char was calculated. The results show that the alkali-treated HZSM-5 catalyst retains typical MFI topology structure and forms a certain number of mesoporous. At the same time, the bio-oil organic phase made with modified HZSM-5 (after 1 h treatment) achieves a higher yield rate and better physical properties. The content of hydrocarbons increases significantly to 37.67% mainly with the increase of mononuclear aromatics. In addition, modified HZSM-5 catalyst (after 1 h treatment) has a better effect on the removal of acid, aldehyde and ketone contained in the bio-oil organic phase, which improves stability of the bio-oil with calorific value of 35.32 MJ/kg. The amount of coke in the HZSM-5 zeolite after 1 h alkali treatment obviously decreases.
- bio-oil,
- alkali-treated HZSM-5,
- catalytic upgrading
1. [1]
  XU Ying, WANG Tie-jun, MA Long-long, ZHANG Qi, CHEN Guan-yi. Technology of bio-oil preparation by vacuum pyrolysis of pine straw[J]. Trans Chin Soc Agric Eng, 2013,29(1):196-201.
2. [2]
  ZHU Xi-feng. Research development of biomass fast pyrolysis[J]. J Circ Syst, 2013,1(1):32-37.
3. [3]
  El-BABARY M H, PHILIP H S, LEONARD I. Characterization of fast pyrolysis bio-oils produced from pretreated pine wood[J]. Appl Biochem Biotechnol, 2009,154(1):3-13.
4. [4]
  NIU X J, GAO J, MIAO Q, DONG M, WANG G F, FAN W B, QIN Z F, WANG J G. Influence of preparation method on the performance of Zn-containing HZSM-5 catalysts in methanol-to-aromatics[J]. Microporous Mesoporous Mater, 2014,197:252-261. doi: 10.1016/j.micromeso.2014.06.027
5. [5]
  GUO Xiao-Ya, YAN Yong-jie. Study on catalytic cracking of bio-oil pyrolyzed from biomass[J]. Chem React Eng Technol, 2005,21(3):227-233.
6. [6]
  GROEN J C, ZHU W, BROUWER S, HUYNINK S, KAPTEIJN F, MOULIJN J. Direct demonstration of enhanced diffusion in mesoporous ZSM-5 zeolite obtained via controlled desilication[J]. J Am Chem Soc, 2007,129(2):355-360. doi: 10.1021/ja065737o
7. [7]
  PENG Peng, ZHANG Zhan-quan, WANG You-he, FAZLE S, YAN Zi-feng. Hierarchical molecular sieves:Synthesis and catalytic applications[J]. Prog Chem, 2013,25(12):2029-2037.
8. [8]
  SOHRAB F, MORTEZA S, CAVUS F. Improvement of HZSM-5 performance by alkaline treatments:Comparative catalytic study in the MTG reactions[J]. Fuel, 2014,116(2014):529-537.
9. [9]
  WEI Y, PETRA E, DAVID J L, MATTEO L M, GLENN J, KRIJN P. Enhanced catalytic performance of zeolite ZSM-5 for conversion of methanol to dimethyl ether by combining alkaline treatment and partial activation[J]. Appl Catal A:Gen, 2015,504:211-219. doi: 10.1016/j.apcata.2014.12.027
10. [10]
  FAN Yong-sheng, CAI Yi-xi, LI Xiao-hua, YU Ning, YIN Hai-yun. Catalytic upgrading of pyrolytic vapors from rape straw vacuum pyrolysis[J]. Trans Chin Soc Agric Mach, 2014,45(12):234-240. doi: 10.6041/j.issn.1000-1298.2014.12.035
11. [11]
  FAN Y S, CAI Y X, LI X H, YIN H Y, YU N. R ape straw as a source of bio-oil via vacuum pyrolysis:Optimization of bio-oil yield using orthogonal design method and characterization of bio-oil[J]. J Anal Appl Pyrolysis, 2014,106(3):63-70.
12. [12]
  FU T, ZHOU H, LI Z. Effect of particle morphology for ZSM-5 zeolite on the catalytic conversion of methanol to gasoline-range hydrocarbons[J]. Catal Lett, 2016,146(10):1973-1983. doi: 10.1007/s10562-016-1841-3
13. [13]
  YANG Ya, GUO Qing-jie, YANG Lin, ZHANG Liang, WANG Xu-yun, ZHANG Xiu-li. Catalytic cracking of chlorella over HZSM-5 zeolite modified by desilication in alkalille medium[J]. Acta Energ Sin, 2016,37(1):171-177.
14. [14]
  XU Qing-li, ZHAO Jun, LI Hong-yu, WANG Fu, YAN Yong-jie. Catalytic cracking of bio-oil upgrading mechanism[J]. J Shenyang Univ, 2012,24(2):15-17.
15. [15]
  AHO A, KUMAR N, LASHKUL A V, ERANEN K, ZIOLEK M, DECYK P, SALMI T, HOLMBOM B. Catalytic upgrading of woody biomass derived pyrolysis vapors over iron modified zeolites in a dual-fluidized bed reactor[J]. Fuel, 2010,89(8):1992-2000. doi: 10.1016/j.fuel.2010.02.009
16. [16]
  ZHANG L H, XU C B, PASCALE C. Overview of recent advances in thermo-chemical conversion of biomass[J]. Energ Convers Manage, 2010,251(5):969-982.
17. [17]
  GUO Chun-Lei, FANG Xiang-chen, JIA Li-ming, LIU Quan-jie, ZHAO Xiao-dong. Development of zeolitic reforming catalyst[J]. Prog Chem, 2012,31(4):825-832.
18. [18]
  WANG J, GRONE J C. Facile synthesis of ZSM-5 composites with hierarchical poposity[J]. J Mater Chem, 2008,18(4):468-478. doi: 10.1039/B711847C
19. [19]
  FAN Yong-sheng. Basic study on vacuum pyrolysis and catalytic transformation of biomass for preparation of bio-oil[D]. Jiangsu:Jiangsu University, 2016.
20. [20]
  KUZNETSOV B N. Deactivation of catalysts for fossil coal and biomass conversion[J]. Catal Ind, 2009,1(3):250-259. doi: 10.1134/S2070050409030143
21. [21]
  BEATRIZ V, CASTA O P, OLAZAR M, BILBAO J, GAYUBO A G. Deactivating species in the transformation of crude bio-oil with methanol into hydrocarbons on a HZSM-5 catalyst[J]. J Catal, 2012,285(1):304-314. doi: 10.1016/j.jcat.2011.10.004
22. [22]
  SEO G, KIM J H, JANG H G. Methanol-to-olefin conversion over zeolite catalysts:Active intermediates and deactivation[J]. Catal Surv Asia, 2013,17(3):103-118.
23. [23]
  DANOV S M, ESIPOVICH A L, BELOUSOV A S, ROGOZHIN A E. Deactivation of acid catalysts in vapor-phase dehydration of glycerol into acrolein[J]. Russ J Appl Chem, 2014,87(4):461-467. doi: 10.1134/S10704272140400119
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