Citation: Guo Dong ZHENG, Qing Da AN, Qing DING, Xiao HAN, Xi Zhang CAO. ELECTROCARBOXYLATION OF ORGANIC COMPOUNDS WITH CARBON DIOXIDE CATALYZED BY METALLOPORPHYRINS (Ⅰ)——CATALYTIC ACTIVITIES OF METALLOPORPHYRINS FOR ELECTROCARBOXYLATION OF BENZYL CHLORIDE[J]. Chinese Chemical Letters, ;1992, 3(2): 97-98. shu

ELECTROCARBOXYLATION OF ORGANIC COMPOUNDS WITH CARBON DIOXIDE CATALYZED BY METALLOPORPHYRINS (Ⅰ)——CATALYTIC ACTIVITIES OF METALLOPORPHYRINS FOR ELECTROCARBOXYLATION OF BENZYL CHLORIDE

Department of Chemistry, Jilin University, Changchun, 130023

Received Date: 16 October 1991

Fund Project: The research is supported by National Natural Science Foundation of China.

The electrocarboxylation of benzyl chloride with CO₂ catalyzed by metalloporphyrins and the effects of different kinds of central metals and ligands on catalytic activities are reported. These metalloporphyrins whose central metals can form corresponding M (Ⅰ) complexes such as CoTPP, FeTPP have high activities. With water-soluble porphyrin ligands such as TPPS, TTMAPI, the corresponding metalloporphyrins have high catalytic activity. Electron-with-drawing groups on the porphyrin ring cause the lowering of activity.
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