Citation: NIU Xin, XIAO Jun. Nitrogen transformation in chemical looping combustion of sewage sludge[J]. Journal of Fuel Chemistry and Technology, ;2017, 45(4): 505-512. shu

Nitrogen transformation in chemical looping combustion of sewage sludge

  • Corresponding author: XIAO Jun, jxiao@seu.edu.cn
  • Received Date: 15 November 2016
    Revised Date: 8 February 2017

    Fund Project: the National Natural Science Foundation of China 51476029the National Natural Science Foundation of China 51561125001the Fundamental Research Funds for the Central Universities KYLX15_0064Scientific Research Foundation of Graduate School of Southeast University YBJJ1543

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  • The experiments were conducted in a bench-scale fluidized-bed reactor. To improve the reactivity of hematite, cement was added. The results show that cement-modified hematite possessed a higher reactivity, leading to an increase in carbon conversion of sewage sludge. Nevertheless, the NO emission also increased as compared to hematite alone. The rise of fuel reactor temperature can intensify both carbon conversion and NO emission. Meanwhile, the rise of steam content can increase carbon conversion and decrease NO emission. Approximately 0.286%-0.768% of nitrogen measured was NO, which is lower than the value in sewage sludge air incineration process.
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    1. [1]

      WERTHER J, OGADA T. Sewage sludge combustion[J]. Prog Energy Combust, 1999,25(1):55-116. doi: 10.1016/S0360-1285(98)00020-3

    2. [2]

      ADANEZ J, ABAD A, GARCIA-LABIANO F, GAYAN P, DE DIEGO L F. Progress in chemical-looping combustion and reforming technologies[J]. Prog Energy Combust, 2012,38(2):215-282. doi: 10.1016/j.pecs.2011.09.001

    3. [3]

      NIU X, SHEN L H, GU H M, JIANG S X, XIAO J. Characteristics of hematite and fly ash during chemical looping combustion of sewage sludge[J]. Chem Eng J, 2015,268:236-244. doi: 10.1016/j.cej.2015.01.063

    4. [4]

      SONG T, SHEN T X, SHEN L H, XIAO J, GU H M, ZHANG S W. Evaluation of hematite oxygen carrier in chemical-looping combustion of coal[J]. Fuel, 2013,104:244-252. doi: 10.1016/j.fuel.2012.09.030

    5. [5]

      SONG T, SHEN L H, XIAO J, CHEN D Q, GU H M, ZHANG S W. Nitrogen transfer of fuel-N in chemical looping combustion[J]. Combust Flame, 2012,159(3):1286-1295. doi: 10.1016/j.combustflame.2011.10.024

    6. [6]

      MENDIARA T, IZQUIERDO MT, ABAD A, DE DIEGO L F, GARCÍA-LABIANO F, GAYÁN P, ADÁNEZ J. Release of pollutant components in CLC of lignite[J]. Int J Greenh Gas Control, 2014,22:15-24. doi: 10.1016/j.ijggc.2013.12.013

    7. [7]

      LEION H, MATTISSON T, LYNGFELT A. Solid fuels in chemical-looping combustion[J]. Int J Greenh Gas Control, 2008,2(2):180-193. doi: 10.1016/S1750-5836(07)00117-X

    8. [8]

      BAO J H, LI Z S, CAI N S. Reduction kinetics of foreign-lon-promoted ilmenite using carbon monoxide (CO) for chemical looping combustion[J]. Ind Eng Chem Res, 2013,52(31):10646-10655. doi: 10.1021/ie4015974

    9. [9]

      BAO J H, LI Z S, CAI N S. Promoting the reduction reactivity of ilmenite by introducing foreign ions in chemical looping combustion[J]. Ind Eng Chem Res, 2013,52(18):6119-6128. doi: 10.1021/ie400237p

    10. [10]

      SONG T, SHEN L H, ZHANG S W, CHEN D Q, XIAO J. Performance of hematite/Ca2Al2SiO7 oxygen carrier in chemical looping combustion of coal[J]. Ind Eng Chem Res, 2013,52(22):7350-7361. doi: 10.1021/ie401142w

    11. [11]

      SONG T, SHEN L H, GUO W J, CHEN D Q, XIAO J. Enhanced reaction performance with hematite/Ca2Al2SiO7 oxygen carrier in chemical looping combustion of coal[J]. Ind Eng Chem Res, 2013,52(28):9573-9585. doi: 10.1021/ie4012613

    12. [12]

      NIU Xin, SHEN Lai-hong, XIAO Jun, JIANG Shou-xi, GU Hai-ming. Chemical looping combustion of sewage sludge with oxygen carrier of cement-modified hematite[J]. J Fuel Chem Technol, 2015,43(11):1402-1408.  

    13. [13]

      ZHAO Zhi-long, TANG Hui-qing, GUO Zhan-cheng. Micro-behavior of the precipitation of metallic Fe in the reduction of Fe2O3 under CO atmosphere[J]. J Iron Steel Res, 2012(11):23-28+62.

    14. [14]

      NIPATTUMMAKUL N, AHMED I, KERDSUWAN S, GUPTA A K. High temperature steam gasification of wastewater sludge[J]. Appl Energy, 2010,87(12):3729-3734. doi: 10.1016/j.apenergy.2010.07.001

    15. [15]

      KELLER M, LEION H, MATTISSON T, LYNGFELT A. Gasification inhibition in chemical-looping combustion with solid fuels[J]. Combust Flame, 2011,158(3):393-400. doi: 10.1016/j.combustflame.2010.09.009

    16. [16]

      NIU Xin. Chemical looping combustion of sewage sludge and nitrogen-phosphorus transformation[D]. Nanjing:Southeast University, 2017.

    17. [17]

      GLARBORG P, JENSEN A D, JOHNSSON J E. Fuel nitrogen conversion in solid fuel fired systems[J]. Prog Energy Combust Sci, 2003,29(2):89-113. doi: 10.1016/S0360-1285(02)00031-X

    18. [18]

      VERMEULEN I, BLOCK C, VANDECASTEELE C. Estimation of fuel-nitrogen oxide emissions from the element composition of the solid or waste fuel[J]. Fuel, 2012,94:75-80. doi: 10.1016/j.fuel.2011.11.071

    19. [19]

      KAMBARA S, TAKARADA T, TOYOSHIMA M, KATO K. Relation between functional forms of coal nitrogen and NOx emissions from pulverized coal combustion[J]. Fuel, 1995,74(9):1247-1253. doi: 10.1016/0016-2361(95)00090-R

    20. [20]

      NIU X, SHEN L H, JIANG S X, GU H M, XIAO J. Combustion performance of sewage sludge in chemical looping combustion with bimetallic Cu-Fe oxygen carrier[J]. Chem Eng J, 2016,294:185-192. doi: 10.1016/j.cej.2016.02.115

    21. [21]

      WARGADALAM V J, LÖFFLER G, WINTER F, HOFBAUER H. Homogeneous formation of NO and N2O from the oxidation of HCN and NH3 at 600-1 000℃[J]. Combust Flame, 2000,120(4):465-478. doi: 10.1016/S0010-2180(99)00107-8

    22. [22]

      ANDRÉS D J, NARROS A, RODRÍGUEZ M E. Behavior of dolomite, olivine and alumina as primary catalysts in air-steam gasification of sewage sludge[J]. Fuel, 2011,90(2):521-527. doi: 10.1016/j.fuel.2010.09.043

    23. [23]

      NIPATTUMMAKUL N, AHMED I I, KERDSUWAN S, GUPTA A K. Hydrogen and syngas production from sewage sludge via steam gasification[J]. Int J Hydrogen Energy, 2010,35(21):11738-11745. doi: 10.1016/j.ijhydene.2010.08.032

    24. [24]

      DENG Wen-yi, YAN Jian-hua, LI Xiao-dong, WANG Fei, CEN Ke-fa. Emission characteristics of pollutants during fluidized-bed incineration of pre-dried sewage sludge[J]. J Zhejiang Univ (Eng Sci), 2008,42(10):1805-1811.  

    25. [25]

      ZHONG Bei-jing, FU Wei-biao. effects of water containing in emulsified heavy oil on NOx and SO2 emissions in boiler[J]. J Combust Sci Technol, 1998,4(4):3-11.  

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