Citation: Shao Kai JIANG, Xian Yuan WANG, Guang Nian LI. HYDROXYLATION OF n-HEXANE CATALYZED BY SUPPORTED Mn (Ⅲ)-PORPHYRIN COMPLEXES[J]. Chinese Chemical Letters, ;1992, 3(7): 503-506. shu

HYDROXYLATION OF n-HEXANE CATALYZED BY SUPPORTED Mn (Ⅲ)-PORPHYRIN COMPLEXES

a Chengdu Institute of Organic Chemistry, Academia Sinica, Chengdu 610015;
b Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Academia Sinica, Shanghai 200032

Received Date: 5 December 1991

Fund Project: Thanks to the National Natural Science Foundation of China for the financial support.

Water-soluble Mn (Ⅲ)-porphyrins supported on various carriers as monooxygenase-like catalysts were used for n-Hexane hydroxylation by PhIO. The hydroxylation yields and XPS measurement of the catalysts indicate that the carriers containing-OH groups have favorable steric and electronic effect on Mn-porphyrins. Some influencing factors and the role of carriers are discussed.
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