Citation: Lai Jun WANG, Ming Hui ZHANG, Wei LI, Ke Yi TAO. Effect of TiO₂ Support on the Composition, Morphology and Catalytic Property of the NiB Amorphous Alloy Catalyst[J]. Chinese Chemical Letters, ;2004, 15(11): 1357-1360. shu

Effect of TiO₂ Support on the Composition, Morphology and Catalytic Property of the NiB Amorphous Alloy Catalyst

College of Chemistry, Nankai University, Tianjin 300071

Received Date: 29 September 2003

Fund Project: The authors are grateful to the NNSFC and NSFTJ for the financial support (20003006 and 031606211).

Both the unsupported and supported NiB amorphous alloy catalysts (NiB and NiB/TiO₂) were prepared by the chemical reduction method. Their catalytic activities were tested by the hydrogenation of sulfolene. The interactions between the NiB alloy and TiO₂ were discussed for the first time by using XRD, ICP, SEM and TEM.
- NiB/TiO₂ amorphous catalyst,
- hydrogenation,
- sulfolene,
- interaction
1. [1]
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19. [19]
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