Citation: ZHANG Li, MENG Peng-tong, WANG Sen, QIN Zhang-feng, WANG Peng-fei, WANG Guo-fu, LI Jun-fen, DONG Mei, FAN Wei-bin, WANG Jian-guo. Synthesis of RUB-13 zeolite and its catalytic performance in the conversion of methanol to olefins[J]. Journal of Fuel Chemistry and Technology, ;2020, 48(9): 1097-1104. shu

Synthesis of RUB-13 zeolite and its catalytic performance in the conversion of methanol to olefins

ZHANG Li ^1,2 ,
MENG Peng-tong ^1,2 ,
WANG Sen ¹ ,
QIN Zhang-feng ^1,, ,
WANG Peng-fei ¹ ,
WANG Guo-fu ¹ ,
LI Jun-fen ^1,, ,
DONG Mei ¹ ,
FAN Wei-bin ¹ ,
WANG Jian-guo ^2,,

1.
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: QIN Zhang-feng, qzhf@sxicc.ac.cn LI Jun-fen, lijunfen@sxicc.ac.cn WANG Jian-guo, iccjgw@sxicc.ac.cn
Received Date: 15 June 2020
Revised Date: 8 August 2020

Fund Project: the National Natural Science Foundation of China 21991092the National Natural Science Foundation of China U1910203the Strategic Priority Research Program of Chinese Academy of Sciences XDA21020500Natural Science Foundation of Shanxi Province of China 201901D211581The project was supported by the National Natural Science Foundation of China (21991092, U1910203, U1862101, 21773281, 21802157), the Strategic Priority Research Program of Chinese Academy of Sciences (XDA21020500) and Natural Science Foundation of Shanxi Province of China (201901D211581)the National Natural Science Foundation of China 21802157the National Natural Science Foundation of China 21773281the National Natural Science Foundation of China U1862101

Figures(6)

RUB-13 zeolites were synthesized by hydrothermal method. The effect of organic structure-directing agent (OSDA), silica source, crystallization temperature and Si/H₂O ratio on the crystal structure was investigated and the catalytic performance of H-RUB-13 in the conversion of methanol to olefins (MTO) was evaluated. The results indicate that with 1, 2, 2, 6, 6-pentamethylpiperidine (PMP) as OSDA and fumed silica as silica source, pure and highly crystalline RUB-13 zeolites with a Si/Al ratio of 100 or 200 can be successfully synthesized by crystallization at 170 ℃, with a H₂O/Si ratio of 100 or 80 in the synthesis gel, respectively. The crystals of the synthesized RUB-13 zeolites display a thin rod-like morphology. As a catalyst in MTO, the high-silica H-Al-B-RUB-13 (Si/Al=200) zeolite exhibits unprecedentedly high selectivity to light olefins at 400 ℃ (54.5% to propene and 97.8% to C_2-5⁼), much better than the traditional H-SAPO-34 and H-ZSM-5 zeolites under similar conditions.
- RUB-13 zeolite,
- hydrothermal synthesis,
- methanol to olefins (MTO),
- catalytic performance
1. [1]
  CUNDY C S, COX P A. The hydrothermal synthesis of zeolites:History and development from the earliest days to the present time[J]. Chem Rev, 2003,103(3):663-702. doi: 10.1021/cr020060i
2. [2]
  CORMA A. State of the art and future challenges of zeolites as catalysts[J]. J Catal, 2003,216(1/2):298-312.
3. [3]
  MU Xu-hong, WANG Dian-zhong, WANG Yong-rui, LIN Min, CHENG Shi-biao, SHU Xing-tian. Nanosized molecular sieves as petroleum refining and petrochemical catalysts[J]. Chin J Catal, 2013,34(1):69-79.
4. [4]
  CHENG Zhi-lin, CHAO Zi-sheng, WAN Hui-lin. Progress in the research of zeolite membrane on gas separation[J]. Prog Chem, 2004,16(1):61-67.
5. [5]
  ZHU Q, KONDO J N, OHNUMA R, KUBOTA Y, YAMAGUCHI M, TATSUMI T. The study of methanol-to-olefin over proton type aluminosilicate CHA zeolites[J]. Microporous Mesoporous Mater, 2008,112(1/3):153-161.
6. [6]
  ZHU Q, HINODE M, YOKOI T, KONDO J N, KONDO Y, TATSUMI T. Methanol-to-olefin over gallosilicate analogues of chabazite zeolite[J]. Microporous Mesoporous Mater, 2008,116(1/3):253-257.
7. [7]
  LIANG J, LI H, ZHAO S, GUO W, WANG R, YING M. Characteristics and performance of SAPO-34 catalyst for methanol-to-olefin conversion[J]. Appl Catal, 1990,64:31-40. doi: 10.1016/S0166-9834(00)81551-1
8. [8]
  ZHU Q, KONDO J N, TATSUMI T, INAGAKI S, OHNUMA R, KUBOTA Y, SHIMODAIRA Y, DOMEN K. A comparative study of methanol to olefin over CHA and MTF zeolites[J]. J Phys Chem C, 2007,111(14):5409-5415. doi: 10.1021/jp063172c
9. [9]
  TANG Jun-qin, YE Li-ping, YING Wei-yong, FANG Ding-ye. Performances of SAPO-34 catalysts with different ratios of Si to Al in methanol-to-olefins[J]. Petrochem Technol, 2010,39(1):22-27.
10. [10]
  PARK J W, LEE J Y, KIM K S, HONG S B, SEO G. Effects of cage shape and size of 8-membered ring molecular sieves on their deactivation in methanol-to-olefin (MTO) reactions[J]. Appl Catal A:Gen, 2008,339(1):36-44. doi: 10.1016/j.apcata.2008.01.005
11. [11]
  IVANOVA S, LEBRUN C, VANHAECKE E, PHAM-HUU C, LOUIS B. Influence of the zeolite synthesis route on its catalytic properties in the methanol to olefin reaction[J]. J Catal, 2009,265(1):1-7.
12. [12]
  BLEKEN F L, CHAVAN S, OLSBYE U, BOLTZ M, OCAMPO F, LOUIS B. Conversion of methanol into light olefins over ZSM-5 zeolite:Strategy to enhance propene selectivity[J]. Appl Catal A:Gen, 2012,447:178-185.
13. [13]
  YOKOI T, YOSHIOKA M, IMAI H, TATSUMI T. Diversification of RTH-type zeolite and its catalytic application[J]. Angew Chem Int Ed, 2009,48(52):9884-9887. doi: 10.1002/anie.200905214
14. [14]
  YOSHIOKA M, YOKOI T, LIU M, IMAI H, INAGAKI S, TATSUMI T. Preparation of RTH-type zeolites with the amount and/or kind of organic structure-directing agents (OSDA):Are OSDAs indispensable for the crystallization?[J]. Microporous Mesoporous Mater, 2012,153:70-78. doi: 10.1016/j.micromeso.2011.12.024
15. [15]
  LIU M, YOKOI T, YOSHIOKA M, IMAI H, KONDO J N, TATSUMI T. Differences in Al distribution and acidic properties between RTH-type zeolites synthesized with OSDAs and without OSDAs[J]. Phys Chem Chem Phys, 2014,16(9):4155-4164. doi: 10.1039/c3cp54297a
16. [16]
  ZHANG L, WANG S, SHI D, QIN Z, WANG P, WANG G, LI J, DONG M, FAN W, WANG J. Methanol to olefins over H-RUB-13 zeolite:Regulation of framework aluminum siting and acid density and their relationship to the catalytic performance[J]. Catal Sci Technol, 2020,10(6):1835-1847. doi: 10.1039/C9CY02419K
17. [17]
  JIA Yan-ping, MA Jiao, ZHANG Lan-he, DONG Chang-qing, WANG Xiao-qiang. Application progress on porous silica material[J]. Bull. Chin Ceram Soc, 2014,33(12):3206-3212.
18. [18]
  LANDRY C C, TOLBERT S H, GALLIS K W, MONNIER A, STUCKY G D, NORBY P, HANSON J C. Phase transformations in mesostructured silica/surfactant composites. Mechanisms for change and applications to materials synthesis[J]. Chem Mater, 2001,13(5):1600-1608. doi: 10.1021/cm000373z
19. [19]
  VORTMANN S, MARLER B, GIES H, DANIELS P. Synthesis and crystal structure of the new borosilicate zeolite RUB-13[J]. Microporous Mesoporous Mater, 1995,4(2/3):111-121.
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