Citation: ZHANG Li, MENG Peng-tong, WANG Sen, QIN Zhang-feng, WANG Peng-fei, WANG Guo-fu, LI Jun-fen, DONG Mei, FAN Wei-bin, WANG Jian-guo. Synthesis of RUB-13 zeolite and its catalytic performance in the conversion of methanol to olefins[J]. Journal of Fuel Chemistry and Technology, ;2020, 48(9): 1097-1104. shu

Synthesis of RUB-13 zeolite and its catalytic performance in the conversion of methanol to olefins

ZHANG Li ^1,2 ,
MENG Peng-tong ^1,2 ,
WANG Sen ¹ ,
QIN Zhang-feng ^1,, ,
WANG Peng-fei ¹ ,
WANG Guo-fu ¹ ,
LI Jun-fen ^1,, ,
DONG Mei ¹ ,
FAN Wei-bin ¹ ,
WANG Jian-guo ^2,,

1.
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: QIN Zhang-feng, qzhf@sxicc.ac.cn LI Jun-fen, lijunfen@sxicc.ac.cn WANG Jian-guo, iccjgw@sxicc.ac.cn
Received Date: 15 June 2020
Revised Date: 8 August 2020

Fund Project: the National Natural Science Foundation of China 21991092the National Natural Science Foundation of China U1910203the Strategic Priority Research Program of Chinese Academy of Sciences XDA21020500Natural Science Foundation of Shanxi Province of China 201901D211581The project was supported by the National Natural Science Foundation of China (21991092, U1910203, U1862101, 21773281, 21802157), the Strategic Priority Research Program of Chinese Academy of Sciences (XDA21020500) and Natural Science Foundation of Shanxi Province of China (201901D211581)the National Natural Science Foundation of China 21802157the National Natural Science Foundation of China 21773281the National Natural Science Foundation of China U1862101

Figures(6)

RUB-13 zeolites were synthesized by hydrothermal method. The effect of organic structure-directing agent (OSDA), silica source, crystallization temperature and Si/H₂O ratio on the crystal structure was investigated and the catalytic performance of H-RUB-13 in the conversion of methanol to olefins (MTO) was evaluated. The results indicate that with 1, 2, 2, 6, 6-pentamethylpiperidine (PMP) as OSDA and fumed silica as silica source, pure and highly crystalline RUB-13 zeolites with a Si/Al ratio of 100 or 200 can be successfully synthesized by crystallization at 170 ℃, with a H₂O/Si ratio of 100 or 80 in the synthesis gel, respectively. The crystals of the synthesized RUB-13 zeolites display a thin rod-like morphology. As a catalyst in MTO, the high-silica H-Al-B-RUB-13 (Si/Al=200) zeolite exhibits unprecedentedly high selectivity to light olefins at 400 ℃ (54.5% to propene and 97.8% to C_2-5⁼), much better than the traditional H-SAPO-34 and H-ZSM-5 zeolites under similar conditions.
- RUB-13 zeolite,
- hydrothermal synthesis,
- methanol to olefins (MTO),
- catalytic performance
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