Citation: Ping Rong WEI, Tian Zhu JIN, Qing Chuan YANG, Guang Xian XU. CRYSTAL STRUCTURE OF A HETERONUCLEAR LANTHANIDE COMPLEX OF ERBIUM-YTTRIUM AND GLYCINE[ErY(GlY)₆(H₂O)₄](ClO₄)₆5H₂O[J]. Chinese Chemical Letters, ;1991, 3(9): 699-700. shu

CRYSTAL STRUCTURE OF A HETERONUCLEAR LANTHANIDE COMPLEX OF ERBIUM-YTTRIUM AND GLYCINE[ErY(GlY)₆(H₂O)₄](ClO₄)₆5H₂O

Research Centre of Rare Earth Chemistry Peking University Beijing 100871

Received Date: 29 July 1991

The title complex [ErY(Gly)₆(H₂O)₄](ClO₄)₆ 5H₂O has been synthesized.Its crystal structure has been determined by X-ray diffraction method.The crystal is triclinic with space group P1.The unit cell parameters are as follows:a=11.518(4), b=14.105(7), c=15.530(6)Å, α=96.61(3), β=102.74(3), γ=105.70(3)°, V=2327.7(17)Å³, Z=2, Dc=2.091g/cm³.The structure has been refined to a final R of 0.0785.The crystal is an infinite chain complex, in which four carboxyl groups from glycine molecules bridge the Er(Ⅲ)and Y(Ⅲ) ion, other two carboxyl groups bridge two adjacent Er(Ⅲ)or two Y(Ⅲ)ions.
1. [1]
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3. [3]
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12. [12]
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13. [13]
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14. [14]
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15. [15]
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16. [16]
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17. [17]
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18. [18]
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19. [19]
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20. [20]
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