Citation: LI Bao-ru, YIN Xue-mei, WU Xu, AN Xia, XIE Xian-mei. Montmorillonite supported Ni-Fe catalysts for hydrogen production from steam reforming of ethanol[J]. Journal of Fuel Chemistry and Technology, ;2016, 44(8): 993-1000. shu

Montmorillonite supported Ni-Fe catalysts for hydrogen production from steam reforming of ethanol

College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, China

Corresponding author: XIE Xian-mei, yxm6686@yeah.net
Received Date: 4 February 2016
Revised Date: 12 May 2016

Figures(8)

Ni-Fe/montmorillonite (MMT) catalysts were prepared by impregnation method for hydrogen production via ethanol steam reforming. The catalysts were characterized by XRD, H₂-TPR, and N₂ adsorption-desorption. It was found that Ni-Fe bimetallic catalysts exhibited higher activities and stability than single metallic catalysts due to the well dispersed Ni-Fe, small nickel crystallites and stronger interaction between Ni²⁺ and carrier. The conversion and selectivity were affected by the ratio of Ni to Fe. The 10Ni5Fe/MMT catalyst showed the optimum catalytic performance, its ethanol conversion was 100%, the selectivity of hydrogen gas remained at 72%, and selectivity of CO and CH₄ were significantly decreased at 500℃ during 30h testing. This could be attributed to the promoter Fe, which improves the dispersion of Ni and results in a good ESR activity at low reaction temperature. Small Ni particles can suppress methane formation and Fe addition can enhance the methane reforming with water and water gas shift reaction, resulting in higher selectivity of hydrogen.
- Ni-Fe,
- montmorillonite,
- ethanol,
- water steam reforming,
- hydrogen production
1. [1]
  MOMIRLAN M, VEZIROGLU T N. The properties of hydrogen as fuel tomorrow in sustainable energy system for a cleaner planet[J]. Int J Hydrogen Energy, 2005,30(7):795-802. doi: 10.1016/j.ijhydene.2004.10.011
2. [2]
  GUO Kun, ZHANG Jing-jing, LI Hao-ran, DU Zhu-wei. Hydrogen production by microbial electrolysis cells[J]. Prog Chem, 2010,22(4):748-753.
3. [3]
  WEN Fu-yu, YANG Jin-hui, ZONG Xu, MA Yi, XU Qian, MA Bao-jun, LI Can. Photocatalytic hydrogen production utilizing solar energy[J]. Prog Chem, 2009,21(11):2285-2302.
4. [4]
  LI Hui-qing, ZOU Ji-jun, LIU Chang-jun. Progress in hydrogen generation using plasmas[J]. Prog Chem, 2005,17(1):69-77.
5. [5]
  WU Chuan, ZHANG Hua-min, YI Bao-lian. Recent advances in hydrogen generation with chemical methods[J]. Prog Chem, 2005,17(3):423-429.
6. [6]
  QI Ai-du.Study on hydrogen for methanol oxidation reforming[D].Dalian:Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 1999.
7. [7]
  DELUGA G A, SALGE J R, SCHMIDT L D, VERYKIOS X E. Renewable hydrogen from ethanol by auto-thermal reforming[J]. Science, 2004,303(5660):993-997. doi: 10.1126/science.1093045
8. [8]
  CAVALLARO S, CHIODO V, FRENI S, MONDELLOA N, FRUSTERI F. Performance of Rh/Al₂O₃ catalyst in the steam reforming of ethanol:H₂ production for MCFC[J]. Appl Catal A:Gen, 2003,249(1):119-128. doi: 10.1016/S0926-860X(03)00189-3
9. [9]
  FRUSTERI F, FRENI S, SPADARO L, CHIODOA V, BONURAA G, DONATOA S, CAVALLARO S. H₂ production for MC fuel cell by steam reforming of ethanol over MgO supported Pd, Rh, Ni and Co catalysts[J]. Catal Commun, 2004,5(10):611-615. doi: 10.1016/j.catcom.2004.07.015
10. [10]
  WU Y J, SANTOS J C, LI P, YU J G, CUNHA A F, RODRIGUES A E. Simplified kinetic model for steam reforming of ethanol on a Ni/Al₂O₃ catalyst[J]. Can J Chem Eng, 2014,92(1):116-130. doi: 10.1002/cjce.v92.1
11. [11]
  SUN J M, KARIM A M, MEI D H, ENGELHARD M, BAO X H, WANG Y. New insights into reaction mechanisms of ethanol steam reforming on Co-ZrO₂[J]. App Catal B:Environ, 2015,162:141-148. doi: 10.1016/j.apcatb.2014.06.043
12. [12]
  NI M, LEUNG D Y C, LEUNG M K H. A review on reforming bio-ethanol for hydrogen production[J]. Int J Hydrogen Energy, 2007,32(15):3238-3247. doi: 10.1016/j.ijhydene.2007.04.038
13. [13]
  DAVDA R R, SHABAKER J W, HUBER G W, CORTRIGHT R D, DUMESIC J A. A review of catalytic issues and process conditions for renewable hydrogen and alkanes by aqueous-phase reforming of oxygenated hydrocarbons over supported metal catalysts[J]. App Catal B:Environ, 2005,56(1/2):171-186.
14. [14]
  LIU Shao-wen, LI Yong-dan. Research proceeding for methane reforming for hydrogen[J]. J Wuhan Inst Chem Technol, 2005,27(1):20-24.
15. [15]
  CHEN Xing-quan, ZHAO Tian-sheng. Catalyst progress for CH₄ reforming and CO₂[J]. Ningxia Pet Chem Ind, 2003,22(1):15-17.
16. [16]
  ZHANG Bing-bing.Preparation, properties and applications of several eco-materials based on montmorillonite mineral[D].Inner Mongolia:Inner Mongolia University, 2013.
17. [17]
  HU Z W, HE F H, LIU Y F, DONG C X, WU X M, ZHAO W. Effects of surfactant concentration on alkyl chain arrangements in dry and swollen organic montmorillonite[J]. Appl Clay Sci, 2013,75-76(5):134-140.
18. [18]
  HUO Zheng-wen.Modification of montmorillonite and intercalated proton exchange membrane[D].Dalian:Dalian University of Technology, 2013.
19. [19]
  KIM Y, WEI T, STULTZ J, GOODMAN D. Dissociation of water on a flat, ordered silica surface[J]. Langmuir, 2003,19(4):1140-1142. doi: 10.1021/la020734k
20. [20]
  KIM S H, CHUNG J H, KIM Y T, HAN J, YOON S P, NAM S W, LIM T H, LEE H I. SiO₂/Ni and CeO₂/Ni catalysts for single-stage water gas shift reaction[J]. Int J Hydrogen Energy, 2010,35(7):3136-3140. doi: 10.1016/j.ijhydene.2009.09.091
21. [21]
  SING K S W, EVERETT D H, HAUL R A W, MOSCOU L, PIEROTTI R A, ROUQUEROL J, SIEMIENIEWSKA T. Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity[J]. Pure Appl Chem, 1985,57(4):603-619.
22. [22]
  SHI Qiu-jie, MA Hong-bo, PENG Zi-qing, CHEN Wei-qing, ZHANG Ning. La₂O₂CO₃ supported Ni-Fe catalysts for hydrogen production from steam reforming of ethanol[J]. J Chin Rare Earth Soc, 2012,30(1):21-27. doi: 10.1016/S1002-0721(10)60631-X
23. [23]
  YUAN P, FAN M, YANG D, HE H, LIU D, YUAN A, ZHU J, CHEN T. Montmorillonite-supported magnetite nanoparticles for the removal of hexavalent chromium[Cr (VI)]from aqueous solutions[J]. J Hazard Mater, 2009,166(2/3):821-829.
24. [24]
  WU X S, KAWI S. Steam reforming of ethanol to H₂ over Rh/Y₂O₃:Crucial roles of Y₂O₃ oxidizing ability, space velocity, and H₂/C[J]. Energy Environ Sci, 2010,3:334-342. doi: 10.1039/b923978m
25. [25]
  SÁNCHEZ E A, D'ANGELO M A, COMELLI R A. Hydrogen production from glycerol on Ni/Al₂O₃ catalyst[J]. Int J Hydrogen Energy, 2010,35(11):5902-5907. doi: 10.1016/j.ijhydene.2009.12.115
26. [26]
  LEE M S, LEE J Y, LEE D W, DONG J M, LEE K Y. The effect of Zn addition into NiFe₂O₄catalyst for high temperature shift reaction of natural gas reformate assuming no external steam addition[J]. Int J Hydrogen Energy, 2012,37(15):11218-11226. doi: 10.1016/j.ijhydene.2012.04.130
27. [27]
  MENG N, LEUNG D Y C, LEUNG M K H. A review on reforming bio-ethanol for hydrogen production[J]. Int J Hydrogen Energy, 2007,32(15):3238-3247. doi: 10.1016/j.ijhydene.2007.04.038
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