Citation: LIU Yang, ZHU Shan-hui, LI Jun-fen, QIN Zhang-feng, FAN Wei-bin, WANG Jian-guo. Catalytic performance of bimetallic PtCo supported on nanosheets MoS₂ in aqueous-phase reforming of methanol to hydrogen[J]. Journal of Fuel Chemistry and Technology, ;2019, 47(7): 799-805. shu

Catalytic performance of bimetallic PtCo supported on nanosheets MoS₂ in aqueous-phase reforming of methanol to hydrogen

1.
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: ZHU Shan-hui, zhushanhui@sxicc.ac.cn
Received Date: 1 April 2019
Revised Date: 24 April 2019

Fund Project: The project was supported by the National Natural Science Foundation of China (21878321)the National Natural Science Foundation of China 21878321

Figures(6)

Nanosheets MoS₂ with only 6 layers have been successfully synthesized by hydrothermal method and used as support to prepare a series of Pt and PtM (M=Ru, Pd, Co and Ni) bimetallic catalysts for low temperature aqueous-phase reforming of methanol (APRM) to produce hydrogen. Among those catalysts, PtCo supported on MoS₂ nanosheets catalyst exhibited the best performance, and its turnover frequency (TOF) of H₂ formation reached 37142 h^-1 at 220℃. The N₂ adsorption-desorption, TEM, H₂-TPR and XPS results showed that PtCo/MoS₂ performed the highest reduction degree, and the strong electronic interaction between Pt and MoS₂ enhanced the adsorption and activation of methanol on the electron-deficient Pt, thus promoted the methanol reforming.
- hydrogen production,
- aqueous-phase reforming of methanol,
- nanosheets MoS₂,
- bimetallic catalyst,
- dimensional materials
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沈阳化工大学材料科学与工程学院沈阳 110142

Catalytic performance of bimetallic PtCo supported on nanosheets MoS2 in aqueous-phase reforming of methanol to hydrogen

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Catalytic performance of bimetallic PtCo supported on nanosheets MoS₂ in aqueous-phase reforming of methanol to hydrogen