Citation: YAN Zi-Jin, SONG Hua, LI Feng, CHEN Yan-guang. Preparation of Zr modified Ni₂P/SBA-15 catalysts and its hydrodeoxygenation performance[J]. Journal of Fuel Chemistry and Technology, ;2018, 46(7): 809-817. shu

Preparation of Zr modified Ni₂P/SBA-15 catalysts and its hydrodeoxygenation performance

YAN Zi-Jin ¹ ,
SONG Hua ^1,2,, ,
LI Feng ^1,2 ,
CHEN Yan-guang ^1,2

1.
College of Chemistry & Chemical Engineering, Northeast Petroleum University, Daqing 163318, China
2.
Provincial Key Laboratory of Oil & Gas Chemical Technology, Northeast Petroleum University, Daqing 163318, China

Corresponding author: SONG Hua, songhua2004@sina.com
Received Date: 6 March 2018
Revised Date: 25 May 2018

Fund Project: National Natural Science Foundation of China 21276048Innovative Scientific Research Projects of Innovative Practice Base for Postgraduate Training in Northeast Petroleum University YJSCX2017-016NEPUThe project was supported by National Natural Science Foundation of China(21276048) and Innovative Scientific Research Projects of Innovative Practice Base for Postgraduate Training in Northeast Petroleum University(YJSCX2017-016NEPU)

Figures(8)

Ni₂P/ZrO₂-SBA-15(n) and Ni₂P/ZrO₂-SBA-15(m) catalysts were prepared from n-propoxide zirconium (n) and Zr(SO₄)₂(m) as zirconium sources. The catalysts were characterized by X-ray diffraction (XRD), N₂ adsorption specific surface area measurements (BET), CO uptake, X-ray photoelectron spectroscopy (XPS) and NH₃ temperature programmed desorption (NH₃-TPD). The results show that after Zr modification, a new layered structure of ZrP is formed. The introduction of Zr helps to generate more Ni₂P active phase with smaller crystal size, and increase both the acid strength and acid amount of the catalyst. Compared with zirconium n-propoxide, the catalyst prepared from Zr(SO₄)₂ has larger specific surface area, more acid amount, stronger acidity, more ZrP phases, smaller Ni₂P crystal grains and more Ni active sites. The product yields of benzofuran hydrodeoxygenation (BF HDO) given by Ni₂P/ZrO₂-SBA-15(n) and Ni₂P/ZrO₂-SBA-15(m) were 71.5% and 85.9% respectively, which were increased by 14.0% and 28.4% respectively compared with Ni₂P/SBA-15. The BF HDO activity, selectivity and yield of the BF HDO products decreased in the order of Ni₂P/ZrO₂-SBA-15(m) > Ni₂P/ZrO₂-SBA-15(n) > Ni₂P/SBA-15.
- hydrodeoxygenation,
- Ni₂P,
- zirconium,
- Benzofuran (BF)
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沈阳化工大学材料科学与工程学院沈阳 110142

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通讯作者: 陈斌, bchen63@163.com

Preparation of Zr modified Ni₂P/SBA-15 catalysts and its hydrodeoxygenation performance