Citation: YAN Zi-Jin, SONG Hua, LI Feng, CHEN Yan-guang. Preparation of Zr modified Ni₂P/SBA-15 catalysts and its hydrodeoxygenation performance[J]. Journal of Fuel Chemistry and Technology, ;2018, 46(7): 809-817. shu

Preparation of Zr modified Ni₂P/SBA-15 catalysts and its hydrodeoxygenation performance

YAN Zi-Jin ¹ ,
SONG Hua ^1,2,, ,
LI Feng ^1,2 ,
CHEN Yan-guang ^1,2

1.
College of Chemistry & Chemical Engineering, Northeast Petroleum University, Daqing 163318, China
2.
Provincial Key Laboratory of Oil & Gas Chemical Technology, Northeast Petroleum University, Daqing 163318, China

Corresponding author: SONG Hua, songhua2004@sina.com
Received Date: 6 March 2018
Revised Date: 25 May 2018

Fund Project: National Natural Science Foundation of China 21276048Innovative Scientific Research Projects of Innovative Practice Base for Postgraduate Training in Northeast Petroleum University YJSCX2017-016NEPUThe project was supported by National Natural Science Foundation of China(21276048) and Innovative Scientific Research Projects of Innovative Practice Base for Postgraduate Training in Northeast Petroleum University(YJSCX2017-016NEPU)

Figures(8)

Ni₂P/ZrO₂-SBA-15(n) and Ni₂P/ZrO₂-SBA-15(m) catalysts were prepared from n-propoxide zirconium (n) and Zr(SO₄)₂(m) as zirconium sources. The catalysts were characterized by X-ray diffraction (XRD), N₂ adsorption specific surface area measurements (BET), CO uptake, X-ray photoelectron spectroscopy (XPS) and NH₃ temperature programmed desorption (NH₃-TPD). The results show that after Zr modification, a new layered structure of ZrP is formed. The introduction of Zr helps to generate more Ni₂P active phase with smaller crystal size, and increase both the acid strength and acid amount of the catalyst. Compared with zirconium n-propoxide, the catalyst prepared from Zr(SO₄)₂ has larger specific surface area, more acid amount, stronger acidity, more ZrP phases, smaller Ni₂P crystal grains and more Ni active sites. The product yields of benzofuran hydrodeoxygenation (BF HDO) given by Ni₂P/ZrO₂-SBA-15(n) and Ni₂P/ZrO₂-SBA-15(m) were 71.5% and 85.9% respectively, which were increased by 14.0% and 28.4% respectively compared with Ni₂P/SBA-15. The BF HDO activity, selectivity and yield of the BF HDO products decreased in the order of Ni₂P/ZrO₂-SBA-15(m) > Ni₂P/ZrO₂-SBA-15(n) > Ni₂P/SBA-15.
- hydrodeoxygenation,
- Ni₂P,
- zirconium,
- Benzofuran (BF)
1. [1]
  LEON F F, GILLES B, DOROTHÉE L, THOMAS E D, VICTOR T S. Synthesis and hydrodeoxygenation activity of Ni₂P/C-Effect of the palladium salt on lowering the nickel phosphide synthesis temperature[J]. J Catal, 2016,340:154-165. doi: 10.1016/j.jcat.2016.05.016
2. [2]
  SONG H, GONG J, SONG H, LI F, ZHANG J, CHENG Y. Preparation of core-shell structured Ni₂P/Al₂O₃@TiO₂ and its hydrodeoxygenation performance for benzofuran[J]. Catal Commun, 2016,85:1-4. doi: 10.1016/j.catcom.2016.07.005
3. [3]
  CZERNIK S, BRIDGWATER A V. Overview of applications of biomass fast pyrolysis oil[J]. Energy Fuels, 2004,18(2):590-598. doi: 10.1021/ef034067u
4. [4]
  GOYAL H B, SEAL D, SAXENA R C. Bio-Fuels from thermochemical conversion of renewable resources:A review[J]. Renewable Sustainable Energy Rev, 2008,12(2):504-517. doi: 10.1016/j.rser.2006.07.014
5. [5]
  GÉRALDINE L, SOIZIC B, JULIE R, FRÉDÉRIC R, ANNE S M, LAURENCE C, ANNIE P, MICHEL R, SYLVETTE B. Effect of the presence of ionic liquid during the NiMoS bulk preparation in the transformation of decanoic acid[J]. Appl Catal A:Gen, 2017,532:120-132. doi: 10.1016/j.apcata.2016.12.020
6. [6]
  ZHAO H Y, LI D, BUI P, OYAMA S T. Hydrodeoxygenation of guaiacol as model compound for pyrolysis oil on transition metal phosphide hydroprocessing catalysts[J]. Appl Catal A:Gen, 2011,391(1/2):305-310.
7. [7]
  MA H, LI Q, SHI Y, SUN X. Ni₂P/ZrO₂-SBA-15 dibenzothiophene hydrodesulfurization catalysts:Preparation, characterization and evaluation[J]. Trans Tianjin Univ, 2017:1-11.
8. [8]
  LUO N, CAO Y, LI J, GUO W, ZHAO Z. Preparation of Ni₂P/ZrO₂-MCM-41 catalyst and its performance in the hydrodeoxygenation of Jatropha curcas oil[J]. Chem Technol Fuels Oil, 2016,44(1):76-83. doi: 10.1016/S1872-5813(16)30007-X
9. [9]
  LIU D, WANG A, LIU C, ROEL P. Ni₂P/Al₂O₃ hydrodesulfurization catalysts prepared by separating the nickel compound and hypophosphite[J]. Catal Today, 2017,292:133-142. doi: 10.1016/j.cattod.2016.09.019
10. [10]
  FAN G, SHEN M, ZHANG Z, FARUI J. Preparation characterization and catalytic properties of S₂O₈^2-/ZrO₂-CeO₂ solid superacid catalyst[J]. J Rare Earth, 2009,27(3):437-442. doi: 10.1016/S1002-0721(08)60266-5
11. [11]
  LAYMAN K A, BUSSELL M E. Infrared spectroscopic investigation of CO adsorption on silica-supported nickel phosphide catalysts[J]. J Phys Chem B, 2004,108(30):10930-10941. doi: 10.1021/jp037101e
12. [12]
  LEE Y K, OYAMA S T. Comparison of structural properties of SiO₂, Al₂O₃, and C/Al₂O₃ supported Ni₂P catalysts[J]. Stud Surf Sci Catal, 2006,159:357-360. doi: 10.1016/S0167-2991(06)81607-1
13. [13]
  CECILIA J A, INFANTES M A, RODRÍGUEZ C E, JIMÉNEZ L A. A novel method for preparing an active nickel phosphide catalyst for HDS of dibenzothiophene[J]. J Catal, 2009,263(J):4-15.
14. [14]
  GALTAYRIES A, SPORKEN R, RIGA J, BLANCHARD G, CAUDANO R. XPS comparative study of ceria/zirconia mixed oxides:powders and thin film characterisation[J]. J Electron Spectrosc, 1998,88:951-956.
15. [15]
  PAN B, ZHANG Q, DU W, ZHANG W, PAN B, ZHANG Q, XU Z, ZHANG Q. Selective heavy metals removal from waters by amorphous zirconium phosphate:Behavior and mechanism[J]. Water Res, 2007,41(14):3103-3111. doi: 10.1016/j.watres.2007.03.004
16. [16]
  LI K, WANG R J, CHEN J X. Hydrodeoxygenation of anisole over silica-supported Ni₂P, MoP, and NiMoP catalysts[J]. Energy Fuels, 2011,25:854-863. doi: 10.1021/ef101258j
17. [17]
  ZHU T, SONG H, DAI X, SONG H. Preparation of Ni₂P/Al-SBA-15 catalyst and its performance for benzofuran hydrodeoxygenation[J]. Chin J Chem Eng, 2017,25(12):1784-1790. doi: 10.1016/j.cjche.2017.03.027
18. [18]
  LAN L, GE S, LIU K, HOU Y, BAO X. Synthesis of Ni₂P promoted trimetallic NiMoW/γ-Al₂O₃ catalysts for diesel oil hydrotreatment[J]. J Nat Gas Chem, 2011,20:117-122. doi: 10.1016/S1003-9953(10)60173-9
19. [19]
  MOON J S, KIM E G, LEE Y K. Active sites of Ni₂P/SiO₂ catalyst for hydrodeoxygenation of guaiacol:A joint XAFS and DFT study[J]. J Catal, 2014,311:144-152. doi: 10.1016/j.jcat.2013.11.023
20. [20]
  LEE C L, OLLIS D F. Catalytic hydrodeoxygenation of benzofuran and o-ethylphenol[J]. J Catal, 1984,87(2):325-331. doi: 10.1016/0021-9517(84)90193-3
21. [21]
  BENSON S W. Thermochemical Kinetics[M]. New York:Wiley, 1968:23-32.
22. [22]
  GONÇALVES V O O, DE SOUZA P M, DA SILVA V T, NORONHA F B, RICHARD F. Kinetics of the hydrodeoxygenation of cresol isomers over Ni₂P/SiO₂:Proposals of nature of deoxygenation active sites based on an experimental study[J]. Appl Catal B:Environ, 2017,205:357-367. doi: 10.1016/j.apcatb.2016.12.051
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1.
沈阳化工大学材料科学与工程学院沈阳 110142

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通讯作者: 陈斌, bchen63@163.com

Preparation of Zr modified Ni₂P/SBA-15 catalysts and its hydrodeoxygenation performance