Citation: Wang Guanshi, Wang Xiaoyong. Influence of Medium-low Concentration of Ionic Liquid [Bmim][BF₄] on Critical Micellization Concentration and Micelle Structures[J]. Chemistry, ;2017, 80(8): 777-782, 771. shu

Influence of Medium-low Concentration of Ionic Liquid [Bmim][BF₄] on Critical Micellization Concentration and Micelle Structures

Wang Guanshi ,
Wang Xiaoyong ^,

Schoool of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237

Corresponding author: Wang Xiaoyong, xiaoyong@ecust.edu.cn
Received Date: 10 January 2017
Accepted Date: 3 March 2017

Figures(6)

The presence of ionic liquids (ILs) has a significant impact on the aggregation behavior of surfactants in aqueous solution. In this article, micellization of non-ionic surfactant Tween-20 with the presence of middle and low concentration of hydrophilic ionic liquid [bmim][BF₄] (1-butyl-3-methylimidazolium tetrafluoroborate) was investigated. Critical micellization concentration (CMC) of Tween-20 showed an upward trend while increasing concentration of [bmim][BF₄] from 0 to 0.2 mol·L^-1. Aggregation number of Tween-20 micelles decreased with increasing the concentration of [bmim][BF₄], which also indicated that the presence of [bmim][BF₄] had great effect on hindering the micellization of Tween-20. Thermodynamic investigation demonstrated that the micellization of Tween-20 was driven by both entropy and enthalpy, and also showed entropy-enthalpy compensation. Meanwhile, average particle size and micro-viscosity of Tween-20 micelles increased first and then decreased with increasing concentration of [bmim][BF₄] from 0 to 0.2 mol·L^-1, reaching the peak values at c_IL=0.05 mol·L^-1.
- Nonionic surfactant,
- Ionic liquids,
- Critical micellization concentration,
- Aggregation number,
- Particle size,
- Micro viscosity
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Influence of Medium-low Concentration of Ionic Liquid [Bmim][BF₄] on Critical Micellization Concentration and Micelle Structures